Authors: | Antoni, Patrick W. Golz, Christopher Hansmann, Max M. |
Title: | Organic four‐electron redox systems based on bipyridine and phenanthroline carbene architectures |
Language (ISO): | en |
Abstract: | Novel organic redox systems that display multistage redox behaviour are highly sought-after for a series of applications such as organic batteries or electrochromic materials. Here we describe a simple strategy to transfer well-known two-electron redox active bipyridine and phenanthroline architectures into novel strongly reducing four-electron redox systems featuring fully reversible redox events with up to five stable oxidation states. We give spectroscopic and structural insight into the changes involved in the redox-events and present characterization data on all isolated oxidation states. The redox-systems feature strong UV/Vis/NIR polyelectrochromic properties such as distinct strong NIR absorptions in the mixed valence states. Two-electron charge–discharge cycling studies indicate high electrochemical stability at strongly negative potentials, rendering the new redox architectures promising lead structures for multi-electron anolyte materials. |
Subject Headings: | Carbenes Electron donor Redox chemistry Structure elucidation |
Subject Headings (RSWK): | Carbene Charge-transfer-Komplexe Redoxreaktion Strukturaufklärung |
URI: | http://hdl.handle.net/2003/42354 http://dx.doi.org/10.17877/DE290R-24191 |
Issue Date: | 2022-03-17 |
Rights link: | https://creativecommons.org/licenses/by/4.0/ |
Appears in Collections: | Organische Chemie |
Files in This Item:
File | Description | Size | Format | |
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Angew Chem Int Ed - 2022 - Antoni - Organic Four‐Electron Redox Systems Based on Bipyridine and Phenanthroline Carbene.pdf | DNB | 6.53 MB | Adobe PDF | View/Open |
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