| Identification code | 3074 |
| Empirical formula | C25H29FeNO2Si |
| Formula weight | 459.43 |
| Temperature/K | 173 |
| Crystal system | orthorhombic |
| Space group | P212121 |
| a/Å | 7.8104(5) |
| b/Å | 12.1050(9) |
| c/Å | 23.811(2) |
| α/° | 90 |
| β/° | 90 |
| γ/° | 90 |
| Volume/Å3 | 2251.2(3) |
| Z | 4 |
| ρcalcg/cm3 | 1.356 |
| μ/mm‑1 | 0.745 |
| F(000) | 968.0 |
| Crystal size/mm3 | 0.2 × 0.05 × 0.05 |
| Radiation | MoKα (λ = 0.71073) |
| 2Θ range for data collection/° | 4.798 to 53.996 |
| Index ranges | -9 ≤ h ≤ 9, -15 ≤ k ≤ 15, -30 ≤ l ≤ 30 |
| Reflections collected | 17819 |
| Independent reflections | 4885 [Rint = 0.0658, Rsigma = 0.0771] |
| Data/restraints/parameters | 4885/0/275 |
| Goodness-of-fit on F2 | 1.043 |
| Final R indexes [I>=2σ (I)] | R1 = 0.0522, wR2 = 0.0875 |
| Final R indexes [all data] | R1 = 0.0728, wR2 = 0.0948 |
| Largest diff. peak/hole / e Å-3 | 0.43/-0.35 |
| Flack parameter | -0.004(15) |
| Atom | x | y | z | U(eq) |
|---|---|---|---|---|
| Fe1 | 7647.8(8) | 10623.1(5) | 7448.8(3) | 26.13(18) |
| Si1 | 10120.6(16) | 10331.4(11) | 6186.1(5) | 24.1(3) |
| O1 | 11283(4) | 11143(3) | 5792.8(14) | 33.9(8) |
| O2 | 11279(4) | 9308(3) | 6419.4(13) | 32.1(8) |
| N1 | 7926(5) | 13153(3) | 6106.2(16) | 28.1(10) |
| C1 | 9429(5) | 11017(4) | 6837.3(19) | 22.9(11) |
| C2 | 8217(6) | 11905(4) | 6920.3(19) | 26.2(11) |
| C3 | 8317(6) | 12252(4) | 7493(2) | 32.3(11) |
| C4 | 9539(6) | 11599(4) | 7774(2) | 34.8(13) |
| C5 | 10227(5) | 10850(4) | 7373.8(19) | 26.8(11) |
| C11 | 7043(6) | 12379(4) | 6485(2) | 29.3(12) |
| C12 | 6747(7) | 13529(4) | 5671(2) | 41.0(14) |
| C13 | 8603(7) | 14085(4) | 6424(2) | 37.2(14) |
| C14 | 8400(6) | 9920(4) | 5678.8(19) | 25.0(11) |
| C15 | 7940(6) | 10673(4) | 5271.4(19) | 30.9(11) |
| C16 | 6647(7) | 10470(4) | 4870(2) | 38.5(13) |
| C17 | 5850(7) | 9465(4) | 4867(2) | 38.8(13) |
| C18 | 6287(6) | 8632(4) | 5261(2) | 27.5(11) |
| C19 | 7561(6) | 8875(3) | 5675.1(18) | 22.8(9) |
| C20 | 7938(6) | 8023(4) | 6070(2) | 28.9(12) |
| C21 | 7134(7) | 7028(4) | 6046(2) | 34.7(13) |
| C22 | 5906(7) | 6810(4) | 5634(2) | 39.4(14) |
| C23 | 5482(7) | 7594(4) | 5254(2) | 34.0(13) |
| C24 | 12671(9) | 11760(5) | 6002(3) | 63.7(19) |
| C25 | 12364(7) | 8668(4) | 6065(2) | 42.4(13) |
| C6 | 6008(7) | 9403(5) | 7188(2) | 51.5(17) |
| C7 | 5094(6) | 10310(5) | 7395(3) | 55.1(17) |
| C8 | 5603(7) | 10459(5) | 7959(2) | 49.3(16) |
| C9 | 6797(7) | 9659(5) | 8089(2) | 49.0(16) |
| C10 | 7061(7) | 9009(4) | 7613(3) | 53.5(17) |
| Atom | U11 | U22 | U33 | U23 | U13 | U12 |
|---|---|---|---|---|---|---|
| Fe1 | 20.7(3) | 33.3(3) | 24.4(3) | 0.6(3) | 1.4(3) | 0.9(3) |
| Si1 | 17.1(7) | 31.5(7) | 23.7(7) | -0.3(6) | 0.6(5) | -1.9(6) |
| O1 | 24.5(18) | 48(2) | 29(2) | 4.6(17) | 1.0(15) | -8.6(17) |
| O2 | 26.9(18) | 38.5(19) | 31.0(18) | -4.1(17) | 3.0(15) | 7.3(18) |
| N1 | 29(3) | 27(2) | 28(2) | 3.8(17) | -5.6(19) | 3(2) |
| C1 | 15(2) | 28(2) | 26(3) | 2(2) | -1.3(19) | -6(2) |
| C2 | 26(3) | 29(2) | 23(3) | 4(2) | 2(2) | -6(2) |
| C3 | 32(3) | 32(2) | 33(3) | -7(2) | -2(3) | -2(2) |
| C4 | 31(3) | 47(3) | 27(3) | -4(2) | -6(2) | -7(3) |
| C5 | 17(2) | 38(3) | 25(3) | 3(2) | -1.9(19) | -3(2) |
| C11 | 24(3) | 30(3) | 34(3) | -4(2) | -3(2) | 6(2) |
| C12 | 43(3) | 44(3) | 36(3) | 6(3) | -7(3) | 4(3) |
| C13 | 40(3) | 30(3) | 41(3) | 3(2) | -2(3) | -2(3) |
| C14 | 22(3) | 31(3) | 22(3) | 0(2) | 6(2) | 2(2) |
| C15 | 36(3) | 26(2) | 30(3) | 6(2) | -2(2) | -4(3) |
| C16 | 48(3) | 36(3) | 31(3) | 10(3) | -12(2) | -2(3) |
| C17 | 38(3) | 43(3) | 35(3) | 3(3) | -8(2) | -1(3) |
| C18 | 23(3) | 31(3) | 29(3) | -5(2) | 3(2) | -1(2) |
| C19 | 17(2) | 21(2) | 30(2) | 0.6(18) | 6(2) | 5(2) |
| C20 | 23(3) | 30(3) | 34(3) | 1(2) | 3(2) | 0(2) |
| C21 | 28(3) | 28(3) | 48(3) | 5(2) | 9(3) | 6(3) |
| C22 | 35(3) | 28(3) | 55(4) | 0(3) | 10(3) | -3(3) |
| C23 | 26(3) | 39(3) | 38(3) | -9(3) | 0(2) | -5(3) |
| C24 | 53(4) | 76(4) | 62(4) | 23(3) | -13(4) | -33(4) |
| C25 | 32(3) | 51(3) | 45(3) | -11(3) | -2(3) | 16(3) |
| C6 | 38(3) | 75(4) | 41(3) | -13(4) | 14(3) | -35(4) |
| C7 | 20(3) | 79(4) | 67(5) | 31(4) | 1(3) | -8(3) |
| C8 | 43(3) | 53(4) | 52(4) | -9(3) | 32(3) | -3(3) |
| C9 | 43(3) | 68(4) | 36(3) | 26(3) | 0(3) | -13(3) |
| C10 | 38(3) | 33(3) | 89(5) | 5(3) | 18(4) | -6(3) |
| Atom | Atom | Length/Å | Atom | Atom | Length/Å | |
|---|---|---|---|---|---|---|
| Fe1 | C1 | 2.070(4) | C2 | C3 | 1.429(6) | |
| Fe1 | C2 | 2.047(4) | C2 | C11 | 1.498(6) | |
| Fe1 | C3 | 2.043(5) | C3 | C4 | 1.409(7) | |
| Fe1 | C4 | 2.044(5) | C4 | C5 | 1.422(6) | |
| Fe1 | C5 | 2.041(4) | C14 | C15 | 1.379(6) | |
| Fe1 | C6 | 2.052(5) | C14 | C19 | 1.425(6) | |
| Fe1 | C7 | 2.034(5) | C15 | C16 | 1.412(6) | |
| Fe1 | C8 | 2.016(5) | C16 | C17 | 1.367(7) | |
| Fe1 | C9 | 2.032(5) | C17 | C18 | 1.420(7) | |
| Fe1 | C10 | 2.045(5) | C18 | C19 | 1.431(6) | |
| Si1 | O1 | 1.633(3) | C18 | C23 | 1.405(7) | |
| Si1 | O2 | 1.631(3) | C19 | C20 | 1.427(6) | |
| Si1 | C1 | 1.840(5) | C20 | C21 | 1.360(6) | |
| Si1 | C14 | 1.874(5) | C21 | C22 | 1.397(7) | |
| O1 | C24 | 1.407(7) | C22 | C23 | 1.352(7) | |
| O2 | C25 | 1.425(5) | C6 | C7 | 1.400(8) | |
| N1 | C11 | 1.472(6) | C6 | C10 | 1.389(8) | |
| N1 | C12 | 1.460(6) | C7 | C8 | 1.411(8) | |
| N1 | C13 | 1.458(6) | C8 | C9 | 1.379(8) | |
| C1 | C2 | 1.446(6) | C9 | C10 | 1.397(8) | |
| C1 | C5 | 1.436(6) |
| Atom | Atom | Atom | Angle/˚ | Atom | Atom | Atom | Angle/˚ | |
|---|---|---|---|---|---|---|---|---|
| C2 | Fe1 | C1 | 41.13(18) | C13 | N1 | C12 | 110.9(4) | |
| C2 | Fe1 | C6 | 119.7(2) | Si1 | C1 | Fe1 | 133.3(2) | |
| C3 | Fe1 | C1 | 68.99(19) | C2 | C1 | Fe1 | 68.6(2) | |
| C3 | Fe1 | C2 | 40.89(18) | C2 | C1 | Si1 | 130.0(3) | |
| C3 | Fe1 | C4 | 40.34(18) | C5 | C1 | Fe1 | 68.5(2) | |
| C3 | Fe1 | C6 | 150.5(2) | C5 | C1 | Si1 | 124.0(3) | |
| C3 | Fe1 | C10 | 166.0(2) | C5 | C1 | C2 | 105.5(4) | |
| C4 | Fe1 | C1 | 69.38(19) | C1 | C2 | Fe1 | 70.3(2) | |
| C4 | Fe1 | C2 | 68.8(2) | C1 | C2 | C11 | 126.2(4) | |
| C4 | Fe1 | C6 | 169.2(2) | C3 | C2 | Fe1 | 69.4(3) | |
| C4 | Fe1 | C10 | 129.9(2) | C3 | C2 | C1 | 108.2(4) | |
| C5 | Fe1 | C1 | 40.88(17) | C3 | C2 | C11 | 125.5(4) | |
| C5 | Fe1 | C2 | 68.29(19) | C11 | C2 | Fe1 | 125.7(3) | |
| C5 | Fe1 | C3 | 67.80(19) | C2 | C3 | Fe1 | 69.7(3) | |
| C5 | Fe1 | C4 | 40.73(18) | C4 | C3 | Fe1 | 69.9(3) | |
| C5 | Fe1 | C6 | 133.4(2) | C4 | C3 | C2 | 109.0(4) | |
| C5 | Fe1 | C10 | 111.5(2) | C3 | C4 | Fe1 | 69.8(3) | |
| C6 | Fe1 | C1 | 111.87(19) | C3 | C4 | C5 | 107.1(4) | |
| C7 | Fe1 | C1 | 131.2(2) | C5 | C4 | Fe1 | 69.5(3) | |
| C7 | Fe1 | C2 | 108.4(2) | C1 | C5 | Fe1 | 70.6(2) | |
| C7 | Fe1 | C3 | 115.7(2) | C4 | C5 | Fe1 | 69.8(3) | |
| C7 | Fe1 | C4 | 147.1(3) | C4 | C5 | C1 | 110.1(4) | |
| C7 | Fe1 | C5 | 170.9(2) | N1 | C11 | C2 | 112.4(4) | |
| C7 | Fe1 | C6 | 40.1(2) | C15 | C14 | Si1 | 117.7(3) | |
| C7 | Fe1 | C10 | 67.3(2) | C15 | C14 | C19 | 117.6(4) | |
| C8 | Fe1 | C1 | 168.3(2) | C19 | C14 | Si1 | 124.7(3) | |
| C8 | Fe1 | C2 | 128.1(2) | C14 | C15 | C16 | 123.2(5) | |
| C8 | Fe1 | C3 | 105.5(2) | C17 | C16 | C15 | 119.0(5) | |
| C8 | Fe1 | C4 | 113.6(2) | C16 | C17 | C18 | 121.3(5) | |
| C8 | Fe1 | C5 | 148.0(2) | C17 | C18 | C19 | 118.5(4) | |
| C8 | Fe1 | C6 | 67.5(2) | C23 | C18 | C17 | 121.3(5) | |
| C8 | Fe1 | C7 | 40.8(2) | C23 | C18 | C19 | 120.2(4) | |
| C8 | Fe1 | C9 | 39.8(2) | C14 | C19 | C18 | 120.4(4) | |
| C8 | Fe1 | C10 | 67.3(2) | C14 | C19 | C20 | 122.9(4) | |
| C9 | Fe1 | C1 | 151.7(2) | C20 | C19 | C18 | 116.7(4) | |
| C9 | Fe1 | C2 | 165.4(2) | C21 | C20 | C19 | 121.1(5) | |
| C9 | Fe1 | C3 | 126.8(2) | C20 | C21 | C22 | 120.9(5) | |
| C9 | Fe1 | C4 | 106.5(2) | C23 | C22 | C21 | 120.4(5) | |
| C9 | Fe1 | C5 | 117.8(2) | C22 | C23 | C18 | 120.7(5) | |
| C9 | Fe1 | C6 | 67.0(2) | C7 | C6 | Fe1 | 69.3(3) | |
| C9 | Fe1 | C7 | 67.6(2) | C10 | C6 | Fe1 | 69.9(3) | |
| C9 | Fe1 | C10 | 40.1(2) | C10 | C6 | C7 | 108.3(5) | |
| C10 | Fe1 | C1 | 120.3(2) | C6 | C7 | Fe1 | 70.7(3) | |
| C10 | Fe1 | C2 | 152.9(2) | C6 | C7 | C8 | 107.0(5) | |
| C10 | Fe1 | C6 | 39.6(2) | C8 | C7 | Fe1 | 68.9(3) | |
| O1 | Si1 | C1 | 112.04(19) | C7 | C8 | Fe1 | 70.3(3) | |
| O1 | Si1 | C14 | 100.89(19) | C9 | C8 | Fe1 | 70.7(3) | |
| O2 | Si1 | O1 | 110.09(18) | C9 | C8 | C7 | 108.3(5) | |
| O2 | Si1 | C1 | 102.61(19) | C8 | C9 | Fe1 | 69.5(3) | |
| O2 | Si1 | C14 | 114.54(19) | C8 | C9 | C10 | 108.2(5) | |
| C1 | Si1 | C14 | 116.9(2) | C10 | C9 | Fe1 | 70.4(3) | |
| C24 | O1 | Si1 | 123.0(3) | C6 | C10 | Fe1 | 70.4(3) | |
| C25 | O2 | Si1 | 122.7(3) | C6 | C10 | C9 | 108.1(5) | |
| C12 | N1 | C11 | 109.7(4) | C9 | C10 | Fe1 | 69.5(3) | |
| C13 | N1 | C11 | 110.1(4) |
| A | B | C | D | Angle/˚ | A | B | C | D | Angle/˚ | |
|---|---|---|---|---|---|---|---|---|---|---|
| Fe1 | C1 | C2 | C3 | 59.2(3) | C3 | C2 | C11 | N1 | 101.6(5) | |
| Fe1 | C1 | C2 | C11 | -120.3(5) | C3 | C4 | C5 | Fe1 | -59.9(3) | |
| Fe1 | C1 | C5 | C4 | -58.7(3) | C3 | C4 | C5 | C1 | -0.6(5) | |
| Fe1 | C2 | C3 | C4 | 58.9(3) | C5 | C1 | C2 | Fe1 | -58.8(3) | |
| Fe1 | C2 | C11 | N1 | -169.6(3) | C5 | C1 | C2 | C3 | 0.4(5) | |
| Fe1 | C3 | C4 | C5 | 59.8(3) | C5 | C1 | C2 | C11 | -179.1(4) | |
| Fe1 | C4 | C5 | C1 | 59.3(3) | C11 | C2 | C3 | Fe1 | 119.8(5) | |
| Fe1 | C6 | C7 | C8 | -59.6(4) | C11 | C2 | C3 | C4 | 178.7(4) | |
| Fe1 | C6 | C10 | C9 | 59.5(4) | C12 | N1 | C11 | C2 | 176.3(4) | |
| Fe1 | C7 | C8 | C9 | -60.8(4) | C13 | N1 | C11 | C2 | -61.4(5) | |
| Fe1 | C8 | C9 | C10 | -60.0(4) | C14 | Si1 | O1 | C24 | 173.5(4) | |
| Fe1 | C9 | C10 | C6 | -60.1(4) | C14 | Si1 | O2 | C25 | 64.9(4) | |
| Si1 | C1 | C2 | Fe1 | 129.3(4) | C14 | Si1 | C1 | Fe1 | 51.9(4) | |
| Si1 | C1 | C2 | C3 | -171.5(3) | C14 | Si1 | C1 | C2 | -46.0(5) | |
| Si1 | C1 | C2 | C11 | 8.9(7) | C14 | Si1 | C1 | C5 | 143.5(4) | |
| Si1 | C1 | C5 | Fe1 | -128.6(3) | C14 | C15 | C16 | C17 | -2.7(8) | |
| Si1 | C1 | C5 | C4 | 172.7(3) | C14 | C19 | C20 | C21 | -178.7(4) | |
| Si1 | C14 | C15 | C16 | -179.1(4) | C15 | C14 | C19 | C18 | -0.2(6) | |
| Si1 | C14 | C19 | C18 | -178.6(3) | C15 | C14 | C19 | C20 | 179.3(4) | |
| Si1 | C14 | C19 | C20 | 0.9(6) | C15 | C16 | C17 | C18 | 0.7(8) | |
| O1 | Si1 | O2 | C25 | -47.9(4) | C16 | C17 | C18 | C19 | 1.4(8) | |
| O1 | Si1 | C1 | Fe1 | 167.6(3) | C16 | C17 | C18 | C23 | -179.3(5) | |
| O1 | Si1 | C1 | C2 | 69.8(4) | C17 | C18 | C19 | C14 | -1.7(7) | |
| O1 | Si1 | C1 | C5 | -100.8(4) | C17 | C18 | C19 | C20 | 178.8(4) | |
| O1 | Si1 | C14 | C15 | -31.2(4) | C17 | C18 | C23 | C22 | -179.8(5) | |
| O1 | Si1 | C14 | C19 | 147.2(4) | C18 | C19 | C20 | C21 | 0.8(7) | |
| O2 | Si1 | O1 | C24 | -65.1(4) | C19 | C14 | C15 | C16 | 2.4(7) | |
| O2 | Si1 | C1 | Fe1 | -74.3(3) | C19 | C18 | C23 | C22 | -0.5(8) | |
| O2 | Si1 | C1 | C2 | -172.2(4) | C19 | C20 | C21 | C22 | -0.2(8) | |
| O2 | Si1 | C1 | C5 | 17.2(4) | C20 | C21 | C22 | C23 | -0.8(8) | |
| O2 | Si1 | C14 | C15 | -149.4(3) | C21 | C22 | C23 | C18 | 1.1(8) | |
| O2 | Si1 | C14 | C19 | 29.0(4) | C23 | C18 | C19 | C14 | 179.0(4) | |
| C1 | Si1 | O1 | C24 | 48.4(5) | C23 | C18 | C19 | C20 | -0.5(7) | |
| C1 | Si1 | O2 | C25 | -167.3(4) | C6 | C7 | C8 | Fe1 | 60.7(4) | |
| C1 | Si1 | C14 | C15 | 90.6(4) | C6 | C7 | C8 | C9 | 0.0(6) | |
| C1 | Si1 | C14 | C19 | -91.0(4) | C7 | C6 | C10 | Fe1 | -58.8(4) | |
| C1 | C2 | C3 | Fe1 | -59.8(3) | C7 | C6 | C10 | C9 | 0.7(6) | |
| C1 | C2 | C3 | C4 | -0.8(5) | C7 | C8 | C9 | Fe1 | 60.5(4) | |
| C1 | C2 | C11 | N1 | -78.9(6) | C7 | C8 | C9 | C10 | 0.5(6) | |
| C2 | C1 | C5 | Fe1 | 58.9(3) | C8 | C9 | C10 | Fe1 | 59.4(4) | |
| C2 | C1 | C5 | C4 | 0.1(5) | C8 | C9 | C10 | C6 | -0.7(6) | |
| C2 | C3 | C4 | Fe1 | -58.8(3) | C10 | C6 | C7 | Fe1 | 59.2(4) | |
| C2 | C3 | C4 | C5 | 0.9(5) | C10 | C6 | C7 | C8 | -0.4(6) |
| Atom | x | y | z | U(eq) |
|---|---|---|---|---|
| H3 | 7666 | 12831 | 7657 | 39 |
| H4 | 9845 | 11649 | 8160 | 42 |
| H5 | 11088 | 10316 | 7450 | 32 |
| H11A | 6545 | 11770 | 6261 | 35 |
| H11B | 6091 | 12770 | 6675 | 35 |
| H12A | 6347 | 12893 | 5452 | 61 |
| H12B | 7336 | 14049 | 5422 | 61 |
| H12C | 5764 | 13896 | 5846 | 61 |
| H13A | 7667 | 14452 | 6625 | 56 |
| H13B | 9143 | 14611 | 6166 | 56 |
| H13C | 9454 | 13819 | 6695 | 56 |
| H15 | 8521 | 11362 | 5260 | 37 |
| H16 | 6335 | 11024 | 4606 | 46 |
| H17 | 4989 | 9320 | 4595 | 47 |
| H20 | 8765 | 8153 | 6355 | 35 |
| H21 | 7410 | 6473 | 6314 | 42 |
| H22 | 5367 | 6107 | 5620 | 47 |
| H23 | 4631 | 7442 | 4980 | 41 |
| H24A | 13113 | 12243 | 5705 | 95 |
| H24B | 13578 | 11257 | 6126 | 95 |
| H24C | 12288 | 12210 | 6320 | 95 |
| H25A | 12557 | 9065 | 5712 | 64 |
| H25B | 11818 | 7956 | 5986 | 64 |
| H25C | 13463 | 8544 | 6253 | 64 |
| H6 | 5921 | 9107 | 6819 | 62 |
| H7 | 4285 | 10744 | 7195 | 66 |
| H8 | 5194 | 11015 | 8207 | 59 |
| H9 | 7344 | 9566 | 8443 | 59 |
| H10 | 7828 | 8402 | 7584 | 64 |
Experimental
Single crystals of C25H29FeNO2Si [3074] were []. A suitable crystal was selected and [] on a Xcalibur, Sapphire3 diffractometer. The crystal was kept at 173 K during data collection. Using Olex2 [1], the structure was solved with the Superflip [2] structure solution program using Charge Flipping and refined with the XL [3] refinement package using Least Squares minimisation.
Crystal structure determination of [3074]
Crystal Data for C25H29FeNO2Si (M =459.43 g/mol): orthorhombic, space group P212121 (no. 19), a = 7.8104(5) Å, b = 12.1050(9) Å, c = 23.811(2) Å, V = 2251.2(3) Å3, Z = 4, T = 173 K, μ(MoKα) = 0.745 mm-1, Dcalc = 1.356 g/cm3, 17819 reflections measured (4.798° ≤ 2Θ ≤ 53.996°), 4885 unique (Rint = 0.0658, Rsigma = 0.0771) which were used in all calculations. The final R1 was 0.0522 (I > 2σ(I)) and wR2 was 0.0948 (all data).
Refinement model description
Number of restraints - 0, number of constraints - unknown.
Details:
1. Fixed Uiso
At 1.2 times of:
All C(H) groups, All C(H,H) groups
At 1.5 times of:
All C(H,H,H) groups
2.a Secondary CH2 refined with riding coordinates:
C11(H11A,H11B)
2.b Aromatic/amide H refined with riding coordinates:
C3(H3), C4(H4), C5(H5), C15(H15), C16(H16), C17(H17), C20(H20), C21(H21),
C22(H22), C23(H23), C6(H6), C7(H7), C8(H8), C9(H9), C10(H10)
2.c Idealised Me refined as rotating group:
C12(H12A,H12B,H12C), C13(H13A,H13B,H13C), C24(H24A,H24B,H24C), C25(H25A,H25B,
H25C)
This report has been created with Olex2, compiled on 2017.01.04 svn.r3372 for OlexSys. Please let us know if there are any errors or if you would like to have additional features.