Authors: Böhmer, Roland
Döß, A.
Hinze, G.
Schiener, B.
Hemberger, J.
Title: Dielectric relaxation in the fragile viscous liquid state of toluene
Language (ISO): en
Abstract: Dielectric measurements were carried out on viscous toluene covering a frequency range from 0.1 Hz to 1 MHz. In order to suppress the pronounced crystallization tendency of this supercooled liquid it was contained in thin walled capillaries with outer diameters of 300 µm. From the temperature dependence of the characteristic dielectric relaxation times it was found that toluene is one of the most fragile low molecular weight glass-forming liquids, with a fragility index m=105. By comparison with time constants available from other experimental techniques it appears that near the glass transition the dielectric relaxation mode is not the slowest one.
URI: http://hdl.handle.net/2003/25533
http://dx.doi.org/10.17877/DE290R-3310
Issue Date: 1997-08-08
Rights: ©1997 American Institute of Physics
Publisher: American Institute of Physics
URL: http://dx.doi.org/10.1063/1.474567
Citation: Döß, A.; Hinze, G.; Schiener, B.; Hemberger, J.; Böhmer, R.: Dielectric relaxation in the fragile viscous liquid state of toluene. In: Journal of Chemical Physics Jg. 107(1997), S. 1740-1743, doi: 10.1063/1.474567.
Appears in Collections:Böhmer, Roland Prof. Dr.

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