Authors: Kiedrowski, Valeska von
God, Claudia
Knauer, Lena
Strohmann, Carsten
Preut, Hans
Hiersemann, Martin
Title: (2R,4S,5S)-5-Hydroxy-4-methyl-3-oxohept-6-en-2-yl benzoate
Language (ISO): en
Abstract: The title compound, C15H18O4, which crystallizes with two mol­ecules in the asymmetric unit, was obtained in the course of the total synthesis of curvicollides A–C and fusaequisin A. It features the relative configuration of the Western aldol part of the natural products. In the crystal, mol­ecules are linked by C—H...O hydrogen bonds.
Subject Headings: Crystal structure
Total synthesis
Curvicollides A-C
Fusaequisin A
Asymmetric aldol reaction
Paterson aldol reaction
Issue Date: 2017
Appears in Collections:Organische Chemie

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