Authors: | Brieger, Lukas Hermann, Andreas Unkelbach, Christian Strohmann, Carsten |
Title: | Crystal structure and quantum-chemical calculations of a trimethylaluminium–THF adduct |
Language (ISO): | en |
Abstract: | The title compound, trimethyl(tetrahydrofuran-κO)aluminium(III), [Al(CH3)3(C4H8O)], is an addition product of trimethylaluminium and tetrahydrofuran (THF). Instead of a dimeric structure, which is very common for these types of compounds, a monomeric molecular structure is observed. The C—Al—C angles in the molecule are very different from the C—Al—C angles found in dimeric molecular structures, leading to a different symmetry around the AlIII atom. The reasons for these differences are discussed. |
Subject Headings: | Crystal structure Aluminium Trimethylaluminium THF Adduct Monomer Angle |
URI: | http://hdl.handle.net/2003/39102 http://dx.doi.org/10.17877/DE290R-21020 |
Issue Date: | 2018-01-31 |
Rights link: | https://creativecommons.org/licenses/by/2.0/uk/legalcode |
Appears in Collections: | Lehrstühle für Anorganische Chemie |
Files in This Item:
File | Description | Size | Format | |
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lh5865.pdf | 429.98 kB | Adobe PDF | View/Open |
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