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DC Element | Wert | Sprache |
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dc.contributor.author | Wu, Kai | - |
dc.contributor.author | Tessarolo, Jacopo | - |
dc.contributor.author | Baksi, Ananya | - |
dc.contributor.author | Clever, Guido H. | - |
dc.date.accessioned | 2022-09-19T11:49:15Z | - |
dc.date.available | 2022-09-19T11:49:15Z | - |
dc.date.issued | 2022-05-26 | - |
dc.identifier.uri | http://hdl.handle.net/2003/41070 | - |
dc.identifier.uri | http://dx.doi.org/10.17877/DE290R-22918 | - |
dc.description.abstract | Multicomponent metallo-supramolecular assembly allows to rationally combine different building blocks. Discrete multifunctional hosts with an accessible cavity can be prepared in a non-statistical fashion. We employ our shape-complementary assembly (SCA) method to achieve for the first time integrative self-sorting of heteroleptic PdII cages showing guest-tunable circularly polarized luminescence (CPL). An enantiopure helicene-based ligand (M or P configuration) is coupled with a non-chiral emissive fluorenone-based ligand (A or B) to form a series of Pd2L2L’2 assemblies. The modular strategy allows to impart the chiral information of the helicenes to the overall supramolecular system, resulting in CPL from the non-chiral component. Guest binding results in a 4-fold increase of CPL intensity. The principle offers potential to generate libraries of multifunctional materials with applications in molecular recognition, enantioselective photo-redox catalysis and information processing. | en |
dc.language.iso | en | de |
dc.relation.ispartofseries | Angew Chem (Int Ed Engl);61(35) | - |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | - |
dc.subject | Circularly polarized luminescence | en |
dc.subject | Coordination cages | en |
dc.subject | Chirality transfer | en |
dc.subject | Host-guest chemistry | en |
dc.subject | Supramolecular chemistry | en |
dc.subject.ddc | 540 | - |
dc.title | Guest-modulated circularly polarized luminescence by ligand-to-ligand chirality transfer in heteroleptic Pd(II) coordination cages | en |
dc.type | Text | de |
dc.type.publicationtype | article | de |
dcterms.accessRights | open access | - |
eldorado.openaire.projectidentifier | info:eu-repo/grantAgreement/EC/H2020/683083/EU/Reactivity and Assembly of Multifunctional, Stimuli-responsive Encapsulation Structures/RAMSES | de |
eldorado.secondarypublication | true | de |
eldorado.secondarypublication.primaryidentifier | https://doi.org/10.1002/anie.202205725 | de |
eldorado.secondarypublication.primarycitation | K. Wu, J. Tessarolo, A. Baksi, G. H. Clever, Angew. Chem. Int. Ed. 2022, 61, e202205725; Angew. Chem. 2022, 134, e202205725. | de |
Enthalten in den Sammlungen: | Lehrstühle für Anorganische Chemie |
Dateien zu dieser Ressource:
Datei | Beschreibung | Größe | Format | |
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Angew Chem Int Ed - 2022 - Wu - Guest‐modulated Circularly Polarized Luminescence by Ligand‐to‐Ligand Chirality Transfer OA.pdf | 1.67 MB | Adobe PDF | Öffnen/Anzeigen |
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