Knauer, LenaKnorr, MichaelViau, LydieStrohmann, Carsten2020-05-252020-05-252019-12-19http://hdl.handle.net/2003/3912710.17877/DE290R-21045The polymeric title compound, [Cu2(C2H3N)2(C3H6S2)2](PF6)2, represents an example of a one-dimensional coordination polymer resulting from the reaction of [Cu(MeCN)4][PF6] with 1,3-di­thiol­ane. The cationic one-dimensional ribbon consists of two copper(I) centers each ligated by one aceto­nitrile mol­ecule and inter­connected through two bridging 1,3-di­thiol­ane ligands. One S-donor site of each ligand is κ1-bound to Cu, whereas the second S atom acts as a four-electron donor, bridging two Cu atoms in a κ4-bonding mode. The positive charge of each copper cation is compensated for by a hexa­fluorido­phosphate counter-ion. In the crystal, the polymer chains are linked by a series of C—H...F hydrogen bonds, forming a supra­molecular frameworkenActa Acta crystallographica / IUC, International Union of Crystallography. Section E, Crystallographic communications;(2020). E76, 38-41http://creativecommons.org/licenses/by/4.0/Crystal structureCopper complexCoordination polymerThio­etherC—H...F hydrogen bonding540article (journal)