Heider, ChristianWinter, AlinaVoß, ViktoriaVogt, DieterSeidensticker, Thomas2025-03-182025-03-182023-01-20http://hdl.handle.net/2003/4355210.17877/DE290R-25385Combining a tubular flow reactor with a robust homogeneous catalyst enabled running the alcohol amination at unique conditions, i. e., very high temperatures at low residence times. Catalytic activities were thus increased to unprecedented values of >900 h−1 in the synthesis of tertiary dimethylalkylamines directly from alcohols with excellent selectivities exceeding 99 %. Furthermore, several alcohols could be converted to the desired tertiary amines.enChemCatChem; 15(5)https://creativecommons.org/licenses/by/4.0/Homogeneous catalysisFlow chemistryAmine synthesis660ResearchArticle