Eldorado - Repositorium der TU Dortmund
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Aktuellste Veröffentlichungen
Item type:Item, Investigation of MHD oxytactic microorganisms with NEPCMs in rectotrapezoidal enclosure with FEM(Elsevier BV, 2024-01-30) Hussain, Shafqat; Jayavel, Prakash; Almutairi, Bander; Ramesh, KattaNanoparticle-enhanced phase change materials (NEPCMs) have gained significant attention in recent years due to their unique ability to enhance the thermal properties and overall performance of phase change materials (PCMs). The present work investigates the bioconvection flow of nano-encapsulated phase change material within a rectotrapezoidal cavity. The left wall of the is fixed at the constant high temperature whereas the right vertical wall is kept at cold temperature. The higher order Galerkin finite element method (GFEM) has been employed to simulate the proposed problem. The discrete systems of nonlinear equations are linearized by implementing the adaptive Newtons method. Influence of various pertinent parameters such as inclined magnetic field, oxytactic bacteria, radiation and Lewis number has been analyzed. It is observed that the average Sherwood and Nusselt number exhibit a positive correlation with the Hartmann and radiation parameter. Moreover, the average heat transfer exhibits a decreasing trend as the Hartmann, bioconvection Rayleigh and Peclet increase.Item type:Item, Large-field irradiation techniques in Germany: a DGMP Working Group survey on the current clinical implementation of total body irradiation, total skin irradiation and craniospinal irradiation(Elsevier BV, 2024-10-16) Heuchel, Lena; Garbe, Stephan; Lühr, Armin; Shariff, MayaIn 2023, a Germany-wide survey on the current clinical practice of three different large field irradiation techniques (LFIT), namely total body irradiation (TBI), total skin irradiation (TSI) and craniospinal irradiation (CSI), was conducted covering different aspects of the irradiation process, e.g., the irradiation unit and technique, dosimetrical aspects and treatment planning as well as quality assurance. The responses provided a deep insight into the applied approaches showing a high heterogeneity between participating centers for all three large field irradiation techniques. The highest heterogeneity was found for TBI. Here, differences between centers were found in almost every aspect of the irradiation process, e.g., the irradiation technique, the prescription dose, the spared organs at risk and the applied treatment planning method. For TBI, the only agreement was found in the fractionation scheme (2 Gy/fraction, 2 fractions/day) and the dose reduction to the lung. TSI was the rarest of the three LFITs. For TSI, the only agreement was found in the use of 6 MeV when irradiating with electrons. The reported approaches of CSI were closest to standard radiotherapy, using no CSI-specific irradiation techniques or treatment planning methods. For CSI, the only agreement was found in the prescribed dose to the brain (50 – 60 Gy). When asking for future requirements, participating centers considered the lack of standardization as the most important future challenge and suggested to perform (retrospective) patient studies. The results of such studies can then serve as a basis for new and improved guidelines.Item type:Item, Cleavage of carbodicarbenes with N2O for accessing stable diazoalkenes(Wiley, 2024-09-06) He, Yijie; Lyu, Yichong; Tymann, David; Antoni, Patrick W.; Hansmann, Max M.The cleavage of carbophosphinocarbenes and carbodicarbenes with nitrous oxide (N_2O) leads to the formation of room-temperature stable diazoalkenes. The utility of Ph_3P/N_2 and NHC/N_2 ligand exchange reactions were demonstrated by accessing novel benzimidazole- and benzothiazole derived diazoalkenes, which are not accessible by the current state-of-the-art methods. The stable diazoalkenes subsequently allow further ligand exchange reactions at C(0) with carbon monoxide, isocyanide, or a diamidocarbene (DAC). Overall, the combination of hitherto unknown NHC/N_2 and N_2/L (L = DAC, CO, R−NC) ligand exchange reactions at a C(0) center allow the selective functionalization of the carbodicarbene ligand structure which represents a new methodology to rapidly assemble novel carbodicarbenes or cumulenic compounds.Item type:Item, Combination of a viscoelastic and a tribological analysis of a low density polyethylene with a high degree of cross-linking(Wiley, 2024-03-30) Schneck, Franziska; Kruse, Philana O.; Hesse‐Hornich, Daniel; Dias, N. Filipe Lopes; Tillmann, Wolfgang; Jerusalem, Robert; Maricanov, Michail; Katzenberg, Frank; Tiller, Jörg C.; Handge, Ulrich A.Cross-linking of polymers is an efficient method to tailor the end-use properties of polymer materials. Cross-linking using a chemical agent, e.g., dicumyl peroxide (DCP), allows for a spatially uniform network formation in the melt state. In addition, it is also associated with side reactions which influence the final properties of the plastic part. This work investigates the influence of DCP concentration on the tribological properties of a cross-linked low-density polyethylene (LDPE) grade. In particular, high DCP concentrations up to 20 phr are chosen in order to explore the effect of a high degree of cross-linking. The viscoelastic properties below and above the melting temperature are studied in detail to support the interpretation of the tribological results. Rheological investigations allow one to monitor the cross-linking of the long-chain branched LDPE. The data and the subsequent optical analysis show that wear already is significantly reduced at a low DCP concentration of 1 phr because of the covalent bonds caused by cross-linking. A high DCP concentration of 20 phr yields an increase of coefficient of friction which can be explained by the low stiffness and the resulting high contact area in the case of highly cross-linked LDPE.Item type:Item, Eine valide Datengrundlage für die Kindertagesbetreuung(2026-06) Meiner-Teubner, Christiane; Birkel-Barmsen, Janine; Carstens, Yannick; Kopp, Katharina
