Eldorado - Repositorium der TU Dortmund

Ressourcen aus und für Forschung, Lehre und Studium

Bei diesem Service handelt es sich um das Institutionelle Repositorium der Technischen Universität Dortmund. Hier werden Ressourcen aus und für Lehre, Studium und Forschung gespeichert, erschlossen und der Öffentlichkeit zugänglich gemacht.

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Fach- und Universitätsübergreifendes 1319
Fakultäten 13788
Graduate School und Graduiertenkollegs 12
Hochschulverwaltung 1245
Sonderforschungsbereiche 1592

Aktuellste Veröffentlichungen

From open containers to confined supramolecular architectures
(2026) Ocklenburg, David; Craen, David van; Henke, Sebastian
The work will investigate the preparation and characterization of charge-neutral Zn(II) metal organic cages based on bis(bidentate) hydroxyquinolate ligands, with focus on how ligand topology and functionality modulate anion recognition and guest-directed assembly. Building on a charge-neutral [Zn2L2] host-complex presented by our group in 2022, various rational designed ligands were synthesized and self-assembled with Zn(OAc)2 to yield discrete [Zn2L2] architectures and others. The first chapter will introduce three new bis(bidentate) ligands LmN3-H2, LN3-H2 and Lcrown3-H2 which are designed and synthesized to increase the functionality of the parent [Zn2L2] cage. Spectroscopic and computational analysis indicate that expanded π-surfaces preserve the metal organic cages integrity while enabling additional host-guest π-interactions, and a crown-ether functionalized derivative demonstrates heteroditopic ion-pair binding. Second, to address the challenge that strongly chelating oxalate can disrupt metal-ligand assemblies, a more flexible ligand LDB3-H2 was designed and synthesized to afford a robust charge-neutral [Zn2LDB32] host-complex. This container forms a well-defined 1:1 oxalate host-guest complex in solution. UV/Vis titrations quantify binding and competition experiments demonstrate selective oxalate recognition over longer dicarboxylates and monocarboxylates. Dicarboxylates form host-guest complexes in a slow-guest exchange behavior, whereas mono-carboxylates demonstrate fast-exchange. Finally, a tripodal bis(bidentate) ligand, LTP3-H3, enables guest-induced control over nuclearity and topology. Tricarboxylates template direct formation of trinuclear and hexanuclear onion-type host-guest complexes with architecturally appealing supramolecular features. 1H NMR competition experiments reveal observable interconversion of a trinuclear species into a hexanuclear species and give insight into the respective binding affinities. Kinetic studies suggest an associative-dissociative exchange-transformation mechanism with a substantial activation barrier.
Single-shot characterization of ultrafast electron dynamics using photoelectron spectroscopy
(2026) Savio, Sara; Helml, Wolfram; Ilchen, Markus
Core-level photoionization is a fundamental process in light–matter interaction consisting of absorbing a photon by an atom or molecule, ejecting an electron from one of its inner shells, and creating a core-shell vacancy. This vacancy is then filled through various relaxation pro-cesses, which can result in the emission of secondary electrons or energy redistribution within the system. The results presented in this thesis contain technical and methodological advances in characterizing the decay dynamics of double-core holes (DCH) in gaseous neon atoms, which have a very short lifetime, using intense and ultrashort X-ray pulses on the attosecond (10−18 s) scale at the European XFEL (Eu-XFEL). Ultrafast electron dynamics are mapped on a single-shot basis using an angle-resolving electron time-of-flight (e-TOF) spectrometer. A spectrometer was built and commissioned as part of this work and is presented in detail, including technical information and experimentally retrieved performance data. Non-invasive systematic pulse characterization using the angu-lar streaking technique provides spectral and temporal information about the ionizing XFEL pulses with attosecond resolution. This approach enables single-shot DCH probing based on the knowledge of spectro-temporal details about the ionizing pulses. A comprehensive study was conducted to investigate how the contribution of DCH chan-nels varies with X-ray pulse parameters, including pulse duration, pulse energy, and the pho-ton energy centres of the reconstructed spectra. The results show that the yield of the DCH signal increases in such a way that is compatible with the reconstruction of X-ray pulse dura-tions well below the life time of the single-core hole (SCH) Auger decay in neon, which is on the order of 2.4 femtosecond (10−15 s), thus enabling the characterization of such short-lived ionic states in a single shot. Examining the electronic structure of the core-ionized system before relaxation, combined with detailed information about the ionizing pulse, provides the experimental stage for valuable insights into nonlinear X-ray–matter interaction. Thus the ensuing photoabsorption and relaxation channel intensities achievable at high-repetition-rate, attosecond duration XFEL allow to reveal these ultrafast processes on the natural timescale of electron dynamics.
Real-time simulation and control of high-definition matrix headlights for automated driving
(2025) Waldner, Mirko; Bertram, Thorsten; Schierz, Christoph
Modern matrix headlights with up to 1.3 million controllable light sources called pixellights enable precise illumination control and sophisticated lighting functions for automated driving. However, their development, verification and validation present substantial challenges that require real-time headlight simulation and control capabilities to be mastered efficiently in terms of time and cost. This thesis at hand addresses these challenges through three primary contributions: a novel real-time matrix headlight simulation for commercial rendering engines, an intuitive and flexible real-time matrix headlight control algorithm and a comprehensive matrix headlight rapid prototyping and development tool. The developed methods have been extensively validated by testing with real matrix headlights. The first significant contribution is a physically accurate, real-time capable simulation approach that combines standard rendering engine spotlights with Sparse Matrix-Vector Multiplication to be lighting technology-independent. This method achieves real-time performance while maintaining physical accuracy by leveraging established sparse matrix formats and parallel computing algorithms. The second significant contribution is the SuperSampling Control (SSC) algorithm for real-time matrix headlight control of arbitrary lighting functions and beam patterns. SSC synthesizes ray tracing, Supersampling Anti-Aliasing and the MapReduce parallel processing method into an intuitive yet computationally efficient approach for rapidly prototyping arbitrary dynamic lighting functions. The third significant contribution is developing a matrix headlight development tool, which integrates the proposed real-time simulation and control methods. The software supports hybrid development approaches through virtual rapid prototyping and hardware-in-the-loop testing with real matrix headlights. Practical applications are energy-efficient, environment-optimal illumination and observer-specific distortion-free symbol projection with closed-loop feedback control.
Smart access strategies for Data-Centric processing
(2025) Berens, Maximilian; Teubner, Jens; Sattler, Kai-Uwe
Data movement in analytical database systems is a critical bottleneck, driving energy consumption and infrastructure costs. In the context of storage access, this thesis contributes techniques to mitigate these costs through Cooperative Refinement, the symbiotic interplay between indexing and data-centric processing. First, we address the intersection of these two fields: We by analyze probabilistic data structures, such as Bloom filters and binary sketches, as candidates for Processing-in-NAND (PiN) due to their high error tolerance. To expand the applicability of current PiN architectures, we propose a scheme for emulating inequality comparisons inside NAND. To maximize the potential of fine-granular index information, we present early work on Gravity Store, a data-centric in-storage materialization engine for declarative analytics. The second major contribution is Team-based indexing, a generalization of bitmap indexing for selective, high-dimensional range queries. By forming "Teams" of moderately-sized attribute subsets, this strategy improves runtime efficiency and reduces storage overhead compared to traditional indexing. We address the central challenges of efficient index intersection and Team composition. Finally, we introduce TeamBench, a benchmark generator specifically designed to evaluate these index intersection performances at scale.
Experimental and simulative investigations of burr formation in planing of AISI 1045
(2024-07-27) Polus, Gero; Saelzer, Jannis; Pleskun, Heiko; Biermann, Dirk; Brümmer, Andreas
The clearance flow in dry-running vacuum pumps is the main loss mechanism. To reduce the clearance mass flow rate in rarefied gas flows, sawtooth structures transversing to the direction of flow can be utilized. However, due to the sawtooth’s structure size, micro-machining is necessary, whereby burr formation is a central challenge. First, the effectiveness of non-idealized sawtooth structures is investigated, demonstrating a high sensibility of the performance regarding the geometry of the tip. Therefore, burr formation in the cutting process must be minimized. For this reason, a 3D finite element (FE) chip formation model capable of predicting the burr formation is developed. An analysis of the burr formation zone showed positive triaxialities; thus, the triaxiality-dependent Johnson–Cook damage model is utilized. To minimize the mesh-induced error, a convergence analysis is conducted, showing no convergence of the maximum burr height. This is caused by the pathological mesh size dependence of local continuum damage models. A comparison of the cutting experiments and simulations revealed a reasonable prediction of cutting forces. In contrast, the passive force is predicted poorly, which is attributed to the underestimation of the ploughing force for non-elastic simulations. The prediction quality regarding the maximum burr height differs for the investigated cutting speeds, which can be explained by a built-up edge and a change in the machine tool compliance. Thereby, an analysis of the burr formation revealed that the burr height is captured by a non-physical remeshing algorithm and that the burr volume might be a more appropriate characteristic.