Thermodynamics of the molecular polaron

dc.contributor.authorStolze, Joachim
dc.contributor.authorBrandt, Uwe
dc.date.accessioned2008-06-03T10:23:47Z
dc.date.available2008-06-03T10:23:47Z
dc.date.issued1983-10-20
dc.description.abstractThe thermodynamics of the molecular polaron model-a two-level system coupled to a harmonic oscillator-is studied. Close upper and lower bounds to the free energy are derived by means of Tchebycheff-Markov inequalities and are compared with the results of other authors. The 'nearly free' behaviour for high temperatures is confirmed. The self-trapping effects at low temperatures are weaker than predicted earlier. In contrast to the prediction of mean-field theory, the transition between the two temperature regimes is not a sharp phase transition but rather a smooth crossover.en
dc.identifier.citationBrandt, Uwe; Stolze, Joachim: Thermodynamics of the molecular polaron : the transition to self-trapping. In: Journal of Physics C Nr. 29, Jg. 16(1983), S. 5617-5627, doi: 10.1088/0022-3719/16/29/015.de
dc.identifier.doi10.1088/0022-3719/16/29/015
dc.identifier.urihttp://hdl.handle.net/2003/25417
dc.identifier.urihttp://dx.doi.org/10.17877/DE290R-3353
dc.identifier.urlhttp://dx.doi.org/:10.1088/0022-3719/16/29/015
dc.language.isoende
dc.publisherThe Institute of Physicsen
dc.rights©1983 The Institute of Physicsen
dc.subject.ddc510
dc.titleThermodynamics of the molecular polaronen
dc.title.alternativethe transition to self-trappingen
dc.typeTextde
dc.type.publicationtypearticlede
dcterms.accessRightsrestricted
eldorado.identifier.urlhttp://t1.physik.tu-dortmund.de/stolze/publications/JPC_16_5617.pdf

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