Systematic studies on heteroleptic coordination cages

Ebbert, Kristina E.

Systematic studies on heteroleptic coordination cages

dc.contributor.advisor	Clever, Guido H.
dc.contributor.author	Ebbert, Kristina E.
dc.contributor.referee	Merten, Christian
dc.date.accepted	2024-02-26
dc.date.accessioned	2024-05-03T12:04:18Z
dc.date.available	2024-05-03T12:04:18Z
dc.date.issued	2024
dc.description.abstract	Supramolecular coordination cages based on square-planar Pd(II) cations in combination with bis-monodentate ligands equipped with pyridine, respectively isoquinoline donor groups, form a subclass of coordination cages and assemblies that has been extensively studied. In recent years, efforts towards the development of functional coordination cages have been made, with the usual approach to achieve this goal being the incorporation of a functional backbone followed by careful choice of linker and donor-groups. Tuning the donor-groups and linkers allowed the synthesis of heteroleptic coordination cages by designing shape-complementary ligands (SCA). Herbey, this approach has been utilized to form a wide array of heteroleptic coordination assemblies and analyze them in regard to their structure, solvent susceptibility and functional group tolerance. Furthermore, ion-mobility mass spectrometry has been established as a powerful tool in the analysis of complex mixtures of up to ten structurally related supramolecules.	de
dc.identifier.uri	http://hdl.handle.net/2003/42463
dc.identifier.uri	http://dx.doi.org/10.17877/DE290R-24299
dc.language.iso	en	de
dc.subject	Heteroleptic coordination cages	de
dc.subject	Supramolecular chemistry	de
dc.subject	Functional assemblies	de
dc.subject	FRET	de
dc.subject	CPL	de
dc.subject.ddc	540
dc.subject.rswk	Supramolekulare Chemie	de
dc.subject.rswk	Fluoreszenz-Resonanz-Energie-Transfer	de
dc.subject.rswk	Lumineszenz	de
dc.subject.rswk	Zirkularpolarisation	de
dc.title	Systematic studies on heteroleptic coordination cages	de
dc.type	Text	de
dc.type.publicationtype	PhDThesis	de
dcterms.accessRights	open access
eldorado.secondarypublication	false	de

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