Water-soluble organotin compounds

Simple item page
dc.contributor.authorAlashkar, Nour
dc.contributor.authorArca, Massimiliano
dc.contributor.authorAlnasr, Hazem
dc.contributor.authorLutter, Michael
dc.contributor.authorLippolis, Vito
dc.date.accessioned2021-07-19T11:19:39Z
dc.date.available2021-07-19T11:19:39Z
dc.date.issued2020-08-21
dc.description.abstractHerein, we report the syntheses of the water-soluble organotin compounds [{Me2(H)N(CH2)3}2SnX2]Y2 (1, X = Cl, Y = ClO4; 2, X = F, Y = ClO4) and {Me2(H)N(CH2)3}2SnX4 (3, X = Cl; 4, X = F). The compounds were characterized by elemental analysis, electrospray mass spectrometry, 1H, 13C, 19F, and 119Sn NMR spectroscopy, and in the case of compounds 1, 3 and 4, by single-crystal X-ray diffraction analysis. The reaction of compound 2 with fluoride anions in water was investigated by NMR spectroscopy. DFT calculations accompany the experimental work.en
dc.identifier.urihttp://hdl.handle.net/2003/40328
dc.identifier.urihttp://dx.doi.org/10.17877/DE290R-22203
dc.language.isoende
dc.relation.ispartofseriesEuropean journal of inorganic chemistry;2020, Issue 41, pp 3925-3936
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.subjectTinen
dc.subjectFluoridesen
dc.subjectCationsen
dc.subjectLewis acidsen
dc.subjectStructure elucidationen
dc.subjectDensity functional calculationsen
dc.subject.ddc540
dc.titleWater-soluble organotin compoundsen
dc.title.alternativesyntheses, structures and reactivity towards fluoride anion in wateren
dc.typeTextde
dc.type.publicationtypearticlede
dcterms.accessRightsopen access
eldorado.secondarypublicationtruede
eldorado.secondarypublication.primarycitationEuropean journal of inorganic chemistry. 2020, Issue 41, pp 3925-3936en
eldorado.secondarypublication.primaryidentifierhttps://doi.org/10.1002/ejic.202000665de

Files

Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
ejic.202000665.pdf
Size:
2.04 MB
Format:
Adobe Portable Document Format
Description:
Download
License bundle
Now showing 1 - 1 of 1
No Thumbnail Available
Name:
license.txt
Size:
4.85 KB
Format:
Item-specific license agreed upon to submission
Description:
Download

Collections

Lehrstühle für Anorganische Chemie