Palladium-catalyzed synthesis of mixed anhydrides via carbonylative telomerization
| dc.contributor.author | Hares, Kevin | |
| dc.contributor.author | Vogelsang, Dennis | |
| dc.contributor.author | Wernsdörfer, Charlotte S. | |
| dc.contributor.author | Panke, Dennis | |
| dc.contributor.author | Vogt, Dieter | |
| dc.contributor.author | Seidensticker, Thomas | |
| dc.date.accessioned | 2023-03-17T08:25:10Z | |
| dc.date.available | 2023-03-17T08:25:10Z | |
| dc.date.issued | 2022-05-02 | |
| dc.description.abstract | For the first time, mixed carboxylic anhydrides were accessed directly via homogeneous palladium catalysis from 1,3-butadiene and carboxylic acids. Under carbonylative telomerization conditions, the respective mixed 3,8-nonadienoic anhydrides are formed in a single reaction step with yields of up to 82%. These very reactive mixed anhydrides can then be used for consecutive reactions in a one-pot manner and selectively transfer the newly formed unsaturated C9 unit. Possible changes in the proposed mechanism were discussed and in a first example, the mixed anhydrides were utilized to form amides. | en |
| dc.identifier.uri | http://hdl.handle.net/2003/41295 | |
| dc.identifier.uri | http://dx.doi.org/10.17877/DE290R-23138 | |
| dc.language.iso | en | de |
| dc.relation.ispartofseries | Catalysis science & technology;12(12) | |
| dc.rights.uri | https://creativecommons.org/licenses/by/3.0/ | |
| dc.subject.ddc | 660 | |
| dc.title | Palladium-catalyzed synthesis of mixed anhydrides via carbonylative telomerization | en |
| dc.type | Text | de |
| dc.type.publicationtype | article | de |
| dcterms.accessRights | open access | |
| eldorado.secondarypublication | true | de |
| eldorado.secondarypublication.primarycitation | Catal. Sci. Technol., 2022,12, 3992-4000 | de |
| eldorado.secondarypublication.primaryidentifier | https://doi.org/10.1039/D2CY00486K | de |