“Metal-modified base pairs” vs. “metal-mediated pairs of bases”: not just a semantic issue!

dc.contributor.authorLippert, Bernhard
dc.date.accessioned2023-06-19T14:01:27Z
dc.date.available2023-06-19T14:01:27Z
dc.date.issued2022-01-29
dc.description.abstractA “nucleobase pair” is not identical with a “pair of basic ligands”, as only in the first case, the existence of inter-base hydrogen bonds is implied. The cross-linking of two nucleobases or two basic ligands by a metal ion of suitable geometry produces either “metal-modified” or “metal-mediated” species, but in the author’s opinion, this difference is not always properly made. This commentary is an attempt to provide a clearer distinction between the two scenarios.en
dc.identifier.urihttp://hdl.handle.net/2003/41826
dc.identifier.urihttp://dx.doi.org/10.17877/DE290R-23670
dc.language.isoende
dc.relation.ispartofseriesJournal of biological inorganic chemistry;27(2)
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.subjectMetal-modified nucleobase pairsen
dc.subjectMetal-mediated base pairsen
dc.subjectMetal nucleobase cross-linksen
dc.subject.ddc540
dc.title“Metal-modified base pairs” vs. “metal-mediated pairs of bases”: not just a semantic issue!en
dc.typeTextde
dc.type.publicationtypearticlede
dcterms.accessRightsopen access
eldorado.secondarypublicationtruede
eldorado.secondarypublication.primarycitationLippert, B. “Metal-modified base pairs” vs. “metal-mediated pairs of bases”: not just a semantic issue!. J Biol Inorg Chem 27, 215–219 (2022). https://doi.org/10.1007/s00775-022-01926-7de
eldorado.secondarypublication.primaryidentifierhttps://doi.org/10.1007/s00775-022-01926-7de

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