Rotational correlation functions and apparently enhanced translational diffusion in a free energy landscape model for the primary relaxation in glass-forming liquids

dc.contributor.authorBöhmer, Roland
dc.contributor.authorHinze, G.
dc.contributor.authorDiezemann, G.
dc.contributor.authorSillescu, H.
dc.date.accessioned2008-06-12T11:18:07Z
dc.date.available2008-06-12T11:18:07Z
dc.date.issued1998
dc.description.abstractWe explore a simple model for supercooled liquids in which reorientational and translational motions are inherently coupled to the structural relaxation. Several controversial aspects of the molecular motion in glass-forming materials are naturally resolved within the framework of our model. These include the geometry of the molecular reorientations as well as the apparent enhancement of translational diffusion. The breakdown of the Stokes-Einstein relation is thus explained without assuming the existence of local diffusion coefficients.en
dc.identifier.doi10.1103/PhysRevE.57.4398
dc.identifier.urihttp://hdl.handle.net/2003/25528
dc.identifier.urihttp://dx.doi.org/10.17877/DE290R-3411
dc.identifier.urlhttp://dx.doi.org/10.1103/PhysRevE.57.4398
dc.language.isoende
dc.publisherThe American Physical Societyen
dc.rights©1998 The American Physical Societyen
dc.subject.ddc530
dc.titleRotational correlation functions and apparently enhanced translational diffusion in a free energy landscape model for the primary relaxation in glass-forming liquidsen
dc.typeTextde
dc.type.publicationtypearticlede
dcterms.accessRightsrestricted

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