Optically detected Electron Paramagnetic Resonance of Metalloproteins

Börger-Enkisch, Birgit

Optically detected Electron Paramagnetic Resonance of Metalloproteins

dc.contributor.advisor	Suter, Dieter	de
dc.contributor.author	Börger-Enkisch, Birgit	de
dc.contributor.referee	Thomson, A. J.	de
dc.date.accepted	2001
dc.date.accessioned	2004-12-06T11:26:27Z
dc.date.available	2004-12-06T11:26:27Z
dc.date.created	2001-06-29	de
dc.date.issued	2001-08-13	de
dc.description.abstract	Metalloproteins, that is proteins containing metal ions, play a key role in biochemical processess. This thesis presents a novel spectroscopic technique, optically detected electron paramagnetic resonance (ODEPR) spectroscopy, which can be applied to the study of metalloproteins. In this work experimental results from different biological samples are presented, where we focus on the copper protein azurin and the iron-sulfurprotein rubredoxin. In addition, the ODEPR spectra are interpreted by means of a theoretical model, which leads to the determination of key parameters such as the optical polarisation of the involved transitions. This thesis demonstrates that ODEPR spectroscopy can serve to improve our understanding of the electronic structure of metalloproteins, and to complement standard spectroscopy methods.	en
dc.format.extent	5713268 bytes
dc.format.extent	2548069 bytes
dc.format.mimetype	application/postscript
dc.format.mimetype	application/pdf
dc.identifier.uri	http://hdl.handle.net/2003/2340
dc.identifier.uri	http://dx.doi.org/10.17877/DE290R-14805
dc.language.iso	en	de
dc.publisher	Universität Dortmund	de
dc.subject	Elektronenspinresonanz	de
dc.subject	Kohärente Ramanstreuung	de
dc.subject	Azurin	de
dc.subject	Rubredoxin	de
dc.subject	magnetischer Zirkulardichroismus	de
dc.subject	electron paramagnetc resonance	en
dc.subject	Azurin, Rubredoxin	de
dc.subject	magnetic circular dichroism	en
dc.subject	coherent Raman scattering	en
dc.subject	metalloproteins	en
dc.subject	EPR	de
dc.subject.ddc	530	de
dc.title	Optically detected Electron Paramagnetic Resonance of Metalloproteins	en
dc.type	Text	de
dc.type.publicationtype	doctoralThesis	de
dcterms.accessRights	open access

Files

Original bundle

Now showing 1 - 2 of 2

Name:: enkisch.ps
Size:: 5.45 MB
Format:: Postscript Files

Download

Name:: mainsg.pdf
Size:: 2.43 MB
Format:: Adobe Portable Document Format
Description:: DNB

Download

Collections

Experimentelle Physik III