Theory of broadband heteronuclear decoupling in multispin systems

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dc.contributor.authorSuter, Dieter
dc.contributor.authorSchenker, K. V.
dc.contributor.authorPines, A.
dc.date.accessioned2008-05-29T12:45:05Z
dc.date.available2008-05-29T12:45:05Z
dc.date.issued2004-07-13
dc.description.abstractThe Waugh theory of broadband decoupling in NMR for I-S Spin 1/2 pairs is extended to arbitrary spin systems. It is shown that complete decoupling is achieved over a certain bandwidth if the irradiation scheme generates an average Hamiltonian for the I spins whose eigenvectors and eigenvalues are independent of resonance offset. If the observed S spins are only weakly coupled, it is possible to calculate the resulting spectrum directly from the offset dependence of the average Hamiltonian of the isolated I-spin system under the influence of the periodic decoupling sequence. The treatment applies to indirectly observed multiple-quantum transitions as well as to directly observable single-quantum resonance lines.en
dc.identifier.citationSuter, D.; Schenker, K. V.; Pines, A.: Theory of broadband heteronuclear decoupling in multispin systems. In: Journal of Magnetic Resonance Nr. 1, Jg. 73(1987), S. 90-98.de
dc.identifier.doi10.1016/0022-2364(87)90227-7
dc.identifier.urihttp://hdl.handle.net/2003/25322
dc.identifier.urihttp://dx.doi.org/10.17877/DE290R-3486
dc.language.isoende
dc.publisherElsevierde
dc.rightsCopyright © 1987 Published by Elsevier Inc.en
dc.subject.ddc530
dc.titleTheory of broadband heteronuclear decoupling in multispin systemsen
dc.typeTextde
dc.type.publicationtypearticlede
dcterms.accessRightsrestricted
eldorado.identifier.urlhttp://e3.physik.tu-dortmund.de/~suter/eprints/BBdecoupling_Theory.pdf

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