Influence of lithium coordinating additives on the structure of phenyldimethylsilyllithium

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dc.contributor.authorAchternbosch, Moritz
dc.contributor.authorBrieger, Lukas
dc.contributor.authorStrohmann, Carsten
dc.date.accessioned2022-04-12T06:54:06Z
dc.date.available2022-04-12T06:54:06Z
dc.date.issued2021-03-22
dc.description.abstractThe synthesis and structural investigation of two dimethylphenylsilyllithium adducts with coordinating nitrogen donors quinuclidine and 1,3,5-tri-tert-butylhexahydro-1,3,5-triazine (tbtac) are presented. The structures show a comparatively long Si−Li distance and one amongst the shortest in monomeric silyllithiums reported so far, respectively. The structural investigations shed light on the influence of the donating additive for the lithium center on the structure of silyllithium compounds.en
dc.identifier.urihttp://hdl.handle.net/2003/40848
dc.identifier.urihttp://dx.doi.org/10.17877/DE290R-22705
dc.language.isoende
dc.relation.ispartofseriesZ. anorg. allg. Chem.;647(9)
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subjectLithiosilaneen
dc.subjectSilanidesen
dc.subjectLithiumen
dc.subjectSiliconen
dc.subjectReductionsen
dc.subject.ddc540
dc.titleInfluence of lithium coordinating additives on the structure of phenyldimethylsilyllithiumen
dc.typeTextde
dc.type.publicationtypearticlede
dcterms.accessRightsopen access
eldorado.secondarypublicationtruede
eldorado.secondarypublication.primarycitationM. Achternbosch, L. Brieger, C. Strohmann, Z. Anorg. Allg. Chem. 2021, 647, 979.de
eldorado.secondarypublication.primaryidentifierhttps://doi.org/10.1002/zaac.202100031de

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