Far-off-resonance averaging of dipolar interactions in solids

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dc.contributor.authorBöhmer, Roland
dc.contributor.authorChang, I.
dc.contributor.authorDiezemann, G.
dc.contributor.authorHinze, G.
dc.contributor.authorSillescu, H.
dc.date.accessioned2008-06-18T11:17:24Z
dc.date.available2008-06-18T11:17:24Z
dc.date.issued1997
dc.description.abstractThe far-off-resonance performance of several line-narrowing sequences is investigated. Both theoretically and experimentally, it is found that transverse relaxation times, dominated by dipole–dipole interactions, are most effectively prolonged not only on-resonance but also for certain, generally large, resonance offsets. These correspond to a situation when, during the basic pulse separation, the frequency offset rotates the toggling-frame Hamiltonian by multiples of 180°. The implications of these results for the study of macroscopic translational diffusion using static-field-gradient NMR are discussed.en
dc.identifier.citationChang, I.; Diezemann, G.; Hinze, G.; Böhmer, R.; Sillescu, H.: Far-off-resonance averaging of dipolar interactions in solids. Journal of Magnetic Resonance Nr. 1, Jg. 124(1997), S. 165-171, doi: 10.1006/jmre.1996.1023.de
dc.identifier.doi10.1006/jmre.1996.1023
dc.identifier.urihttp://hdl.handle.net/2003/25711
dc.identifier.urihttp://dx.doi.org/10.17877/DE290R-3306
dc.identifier.urlhttp://dx.doi.org/10.1006/jmre.1996.1023
dc.language.isoende
dc.publisherAcademic Pressen
dc.rightsCopyright © 1997 Academic Press. All rights reserved.en
dc.subject.ddc530
dc.titleFar-off-resonance averaging of dipolar interactions in solidsen
dc.typeTextde
dc.type.publicationtypearticlede
dcterms.accessRightsrestricted

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