Cycloadditions of diazoalkenes with P4 and tBuCP: access to diazaphospholes

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dc.contributor.authorHauer, Sebastian
dc.contributor.authorReitz, Justus
dc.contributor.authorKoike, Taichi
dc.contributor.authorHansmann, Max M.
dc.contributor.authorWolf, Robert
dc.date.accessioned2025-04-25T14:12:00Z
dc.date.available2025-04-25T14:12:00Z
dc.date.issued2024-07-01
dc.description.abstractDiazoalkenes readily react with tert-butylphosphaalkyne (tBuCP) and white phosphorus (P4) to afford novel phosphorus heterocycles, 3H-1,2,4-diazamonophospholes and 1,2,3,4-diazadiphospholes. Both species represent rare examples of neutral heterophospholes. The mechanism of formation and the electronic structures of these formal (3+2) cycloaddition products were analyzed computationally. The new phospholes form structurally diverse coordination compounds with transition metal and main group elements. Given the growing number of stable diazoalkenes, this work offers a straightforward route to neutral aza(di-)phospholes as a new ligand class.en
dc.identifier.urihttp://hdl.handle.net/2003/43684
dc.identifier.urihttp://dx.doi.org/10.17877/DE290R-25457
dc.language.isoen
dc.relation.ispartofseriesAngewandte Chemie. International edition; 63(38)
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.subjectDiazoalkenesen
dc.subjectmain-group chemistryen
dc.subjectazaphospholesen
dc.subjecttransition-metal chemistryen
dc.subjectnitrogen heterocyclesen
dc.subject.ddc540
dc.titleCycloadditions of diazoalkenes with P4 and tBuCP: access to diazaphospholesen
dc.typeText
dc.type.publicationtypeArticle
dcterms.accessRightsopen access
eldorado.openaire.projectidentifierinfo:eu-repo/grantAgreement/EC/HE/101077332/EU/NAME/CC-CHARGED
eldorado.secondarypublicationtrue
eldorado.secondarypublication.primarycitationS. Hauer, J. Reitz, T. Koike, M. M. Hansmann, R. Wolf, Angew. Chem. Int. Ed. 2024, 63, e202410107. https://doi.org/10.1002/anie.202410107
eldorado.secondarypublication.primaryidentifierhttps://doi.org/10.1002/anie.202410107

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