(2R,4S,5S)-5-Hydroxy-4-methyl-3-oxohept-6-en-2-yl benzoate
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Date
2017
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Abstract
The title compound, C15H18O4, which crystallizes with two molecules in the asymmetric unit, was obtained in the course of the total synthesis of curvicollides A–C and fusaequisin A. It features the relative configuration of the Western aldol part of the natural products. In the crystal, molecules are linked by C—H...O hydrogen bonds.
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Keywords
Crystal structure, Total synthesis, Curvicollides A-C, Fusaequisin A, Asymmetric aldol reaction, Paterson aldol reaction