Crystal structure and quantum-chemical calculations of a tri­methyl­aluminium–THF adduct

Brieger, Lukas; Hermann, Andreas; Unkelbach, Christian; Strohmann, Carsten

Crystal structure and quantum-chemical calculations of a trimethylaluminium–THF adduct

dc.contributor.author	Brieger, Lukas
dc.contributor.author	Hermann, Andreas
dc.contributor.author	Unkelbach, Christian
dc.contributor.author	Strohmann, Carsten
dc.date.accessioned	2020-05-07T07:49:05Z
dc.date.available	2020-05-07T07:49:05Z
dc.date.issued	2018-01-31
dc.description.abstract	The title compound, trimethyl(tetrahydrofuran-κO)aluminium(III), [Al(CH3)3(C4H8O)], is an addition product of trimethylaluminium and tetrahydrofuran (THF). Instead of a dimeric structure, which is very common for these types of compounds, a monomeric molecular structure is observed. The C—Al—C angles in the molecule are very different from the C—Al—C angles found in dimeric molecular structures, leading to a different symmetry around the AlIII atom. The reasons for these differences are discussed.	en
dc.identifier.uri	http://hdl.handle.net/2003/39102
dc.identifier.uri	http://dx.doi.org/10.17877/DE290R-21020
dc.language.iso	en	de
dc.relation.ispartofseries	Acta Cryst. E;74(2)
dc.rights.uri	https://creativecommons.org/licenses/by/2.0/uk/legalcode
dc.subject	Crystal structure	en
dc.subject	Aluminium	en
dc.subject	Trimethylaluminium	en
dc.subject	THF	en
dc.subject	Adduct	en
dc.subject	Monomer	en
dc.subject	Angle	en
dc.subject.ddc	540
dc.title	Crystal structure and quantum-chemical calculations of a trimethylaluminium–THF adduct	en
dc.type	Text	de
dc.type.publicationtype	article	de
dcterms.accessRights	open access
eldorado.secondarypublication	true	de
eldorado.secondarypublication.primarycitation	Brieger, Lukas, Andreas Hermann, Christian Unkelbach, und Carsten Strohmann. "Crystal structure and quantum-chemical calculations of a trimethylaluminium–THF adduct." Acta Cryst. E 74, no. 2 (Februar 2018): 267-70.	de
eldorado.secondarypublication.primaryidentifier	https://doi.org/10.1107/S2056989018001275	de