Crystal structure of the coordination polymer catena-poly[[[(acetonitrile-κN)copper(I)]-μ3-1,3-dithiolane-κ3S:S:S′] hexafluoridophosphate]
| dc.contributor.author | Knauer, Lena | |
| dc.contributor.author | Knorr, Michael | |
| dc.contributor.author | Viau, Lydie | |
| dc.contributor.author | Strohmann, Carsten | |
| dc.date.accessioned | 2020-05-25T12:42:30Z | |
| dc.date.available | 2020-05-25T12:42:30Z | |
| dc.date.issued | 2019-12-19 | |
| dc.description.abstract | The polymeric title compound, [Cu2(C2H3N)2(C3H6S2)2](PF6)2, represents an example of a one-dimensional coordination polymer resulting from the reaction of [Cu(MeCN)4][PF6] with 1,3-dithiolane. The cationic one-dimensional ribbon consists of two copper(I) centers each ligated by one acetonitrile molecule and interconnected through two bridging 1,3-dithiolane ligands. One S-donor site of each ligand is κ1-bound to Cu, whereas the second S atom acts as a four-electron donor, bridging two Cu atoms in a κ4-bonding mode. The positive charge of each copper cation is compensated for by a hexafluoridophosphate counter-ion. In the crystal, the polymer chains are linked by a series of C—H...F hydrogen bonds, forming a supramolecular framework | en |
| dc.identifier.uri | http://hdl.handle.net/2003/39127 | |
| dc.identifier.uri | http://dx.doi.org/10.17877/DE290R-21045 | |
| dc.language.iso | en | de |
| dc.relation.ispartofseries | Acta Acta crystallographica / IUC, International Union of Crystallography. Section E, Crystallographic communications;(2020). E76, 38-41 | |
| dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | |
| dc.subject | Crystal structure | en |
| dc.subject | Copper complex | en |
| dc.subject | Coordination polymer | en |
| dc.subject | Thioether | en |
| dc.subject | C—H...F hydrogen bonding | en |
| dc.subject.ddc | 540 | |
| dc.title | Crystal structure of the coordination polymer catena-poly[[[(acetonitrile-κN)copper(I)]-μ3-1,3-dithiolane-κ3S:S:S′] hexafluoridophosphate] | en |
| dc.type | Text | de |
| dc.type.publicationtype | article | de |
| dcterms.accessRights | open access | |
| eldorado.secondarypublication | true | de |
| eldorado.secondarypublication.primarycitation | Acta crystallographica / IUC, International Union of Crystallography. Section E, Crystallographic communications (2020). E76, 38-41 | en |
| eldorado.secondarypublication.primaryidentifier | https://doi.org/10.1107/S205698901901627X | de |