Crystal structures of di­aquadi-μ-hydroxido-tris­­[tri­methyl­tin(IV)] diformatotri­methyl­stannate(IV) and di-μ-hydroxido-tris­­[tri­methyl­tin(IV)] chloride monohydrate

Otte, Felix; Koller, Stephan G.; Golz, Christopher; Strohmann, Carsten

Crystal structures of diaquadi-μ-hydroxido-tris[trimethyltin(IV)] diformatotrimethylstannate(IV) and di-μ-hydroxido-tris[trimethyltin(IV)] chloride monohydrate

dc.contributor.author	Otte, Felix
dc.contributor.author	Koller, Stephan G.
dc.contributor.author	Golz, Christopher
dc.contributor.author	Strohmann, Carsten
dc.date.accessioned	2020-05-07T07:38:25Z
dc.date.available	2020-05-07T07:38:25Z
dc.date.issued	2016-09-30
dc.description.abstract	The title compounds, [Sn3(CH3)9(OH)2(H2O)2][Sn(CH3)3(CHO2)2] (1) and [Sn3(CH3)9(OH)2]Cl·H2O (2), are partially condensed products of hydrolysed trimethyltin chloride. In the structures of 1 and 2, short cationic tristannatoxanes (C9H29O2Sn3) are bridged by a diformatotrimethyltin anion or a chloride anion, respectively. Hydrogen bridges are present and supposedly stabilize these structures against further polymerization to the known polymeric trimethyltin hydroxide. Especially noteworthy is that the formate present in this structure was formed from atmospheric CO2.	en
dc.identifier.uri	http://hdl.handle.net/2003/39101
dc.identifier.uri	http://dx.doi.org/10.17877/DE290R-21019
dc.language.iso	en	de
dc.relation.ispartofseries	Acta Cryst. E;72(10)
dc.rights.uri	https://creativecommons.org/licenses/by/2.0/uk/legalcode
dc.subject	Crystal structure	en
dc.subject	Tin	en
dc.subject	Trimethyltin hydroxide	en
dc.subject	Formate	en
dc.subject	Chloride	en
dc.subject	Hydrolysis	en
dc.subject	Hydrogen bonding	en
dc.subject.ddc	540
dc.title	Crystal structures of diaquadi-μ-hydroxido-tris[trimethyltin(IV)] diformatotrimethylstannate(IV) and di-μ-hydroxido-tris[trimethyltin(IV)] chloride monohydrate	en
dc.type	Text	de
dc.type.publicationtype	article	de
dcterms.accessRights	open access
eldorado.secondarypublication	true	de
eldorado.secondarypublication.primarycitation	Otte, F; Koller, SG; Golz, C; Strohmann, C (2016): Crystal structures of diaquadi-μ-hydroxido-tris[trimethyltin(IV)] diformatotrimethylstannate(IV) and di-μ-hydroxido-tris[trimethyltin(IV)] chloride monohydrate. Acta Cryst. E 72(10), 1499-1502	de
eldorado.secondarypublication.primaryidentifier	https://doi.org/10.1107/S2056989016014912	de