Molecular structures of enantiomerically-pure (S)-2-(triphenylsilyl)- and (S)-2-(methyldiphenylsilyl)pyrrolidinium salts

Bauer, Jonathan O.; Strohmann, Carsten

Molecular structures of enantiomerically-pure (S)-2-(triphenylsilyl)- and (S)-2-(methyldiphenylsilyl)pyrrolidinium salts

dc.contributor.author	Bauer, Jonathan O.
dc.contributor.author	Strohmann, Carsten
dc.date.accessioned	2020-01-03T13:22:35Z
dc.date.available	2020-01-03T13:22:35Z
dc.date.issued	2017-12-06
dc.description.abstract	Silyl-substituted pyrrolidines have gained increased interest for the design of new catalyst scaffolds. The molecular structures of four enantiomerically-pure 2-silylpyrrolidinium salts are reported. The perchlorate salts of (S)-2-(triphenylsilyl)pyrrolidine [(S)-1·HClO4] and (S)-2-(methyldiphenylsilyl)pyrrolidine [(S)-2·HClO4], the trifluoroacetate (S)-2·TFA, and the methanol-including hydrochloride (S)-1·HCl·MeOH were elucidated by X-ray crystallography and discussed in terms of hydrogen-bond interactions.	en
dc.identifier.uri	http://hdl.handle.net/2003/38488
dc.identifier.uri	http://dx.doi.org/10.17877/DE290R-20407
dc.language.iso	en	de
dc.relation.ispartofseries	Inorganics;Jg.: 5, Heft: 4 \| S. 88-1-88-8
dc.rights.uri	http://creativecommons.org/licenses/by/4.0/
dc.subject	Hydrogen bonds	en
dc.subject	Silicon	en
dc.subject	2-silylpyrrolidines	en
dc.subject	Stereochemistry	en
dc.subject	X-ray crystallography	en
dc.subject.ddc	540
dc.subject.rswk	Wasserstoffbrückenbindung	de
dc.subject.rswk	Silicium	de
dc.subject.rswk	Silylverbindungen	de
dc.subject.rswk	Stereochemie	de
dc.subject.rswk	Röntgenkristallographie	de
dc.title	Molecular structures of enantiomerically-pure (S)-2-(triphenylsilyl)- and (S)-2-(methyldiphenylsilyl)pyrrolidinium salts	en
dc.type	Text	de
dc.type.publicationtype	article	de
dcterms.accessRights	open access
eldorado.secondarypublication	true	de
eldorado.secondarypublication.primarycitation	Inorganics : Jg.: 5, 2017, Heft: 4 \| S. 88-1-88-8	de
eldorado.secondarypublication.primaryidentifier	https://doi.org/10.3390/inorganics5040088	de

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