Molecular structures of enantiomerically-pure (S)-2-(triphenylsilyl)- and (S)-2-(methyldiphenylsilyl)pyrrolidinium salts
dc.contributor.author | Bauer, Jonathan O. | |
dc.contributor.author | Strohmann, Carsten | |
dc.date.accessioned | 2020-01-03T13:22:35Z | |
dc.date.available | 2020-01-03T13:22:35Z | |
dc.date.issued | 2017-12-06 | |
dc.description.abstract | Silyl-substituted pyrrolidines have gained increased interest for the design of new catalyst scaffolds. The molecular structures of four enantiomerically-pure 2-silylpyrrolidinium salts are reported. The perchlorate salts of (S)-2-(triphenylsilyl)pyrrolidine [(S)-1·HClO4] and (S)-2-(methyldiphenylsilyl)pyrrolidine [(S)-2·HClO4], the trifluoroacetate (S)-2·TFA, and the methanol-including hydrochloride (S)-1·HCl·MeOH were elucidated by X-ray crystallography and discussed in terms of hydrogen-bond interactions. | en |
dc.identifier.uri | http://hdl.handle.net/2003/38488 | |
dc.identifier.uri | http://dx.doi.org/10.17877/DE290R-20407 | |
dc.language.iso | en | de |
dc.relation.ispartofseries | Inorganics;Jg.: 5, Heft: 4 | S. 88-1-88-8 | |
dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | |
dc.subject | Hydrogen bonds | en |
dc.subject | Silicon | en |
dc.subject | 2-silylpyrrolidines | en |
dc.subject | Stereochemistry | en |
dc.subject | X-ray crystallography | en |
dc.subject.ddc | 540 | |
dc.subject.rswk | Wasserstoffbrückenbindung | de |
dc.subject.rswk | Silicium | de |
dc.subject.rswk | Silylverbindungen | de |
dc.subject.rswk | Stereochemie | de |
dc.subject.rswk | Röntgenkristallographie | de |
dc.title | Molecular structures of enantiomerically-pure (S)-2-(triphenylsilyl)- and (S)-2-(methyldiphenylsilyl)pyrrolidinium salts | en |
dc.type | Text | de |
dc.type.publicationtype | article | de |
dcterms.accessRights | open access | |
eldorado.secondarypublication | true | de |
eldorado.secondarypublication.primarycitation | Inorganics : Jg.: 5, 2017, Heft: 4 | S. 88-1-88-8 | de |
eldorado.secondarypublication.primaryidentifier | https://doi.org/10.3390/inorganics5040088 | de |