Molecular structures of enantiomerically-pure (S)-2-(triphenylsilyl)- and (S)-2-(methyldiphenylsilyl)pyrrolidinium salts

dc.contributor.authorBauer, Jonathan O.
dc.contributor.authorStrohmann, Carsten
dc.date.accessioned2020-01-03T13:22:35Z
dc.date.available2020-01-03T13:22:35Z
dc.date.issued2017-12-06
dc.description.abstractSilyl-substituted pyrrolidines have gained increased interest for the design of new catalyst scaffolds. The molecular structures of four enantiomerically-pure 2-silylpyrrolidinium salts are reported. The perchlorate salts of (S)-2-(triphenylsilyl)pyrrolidine [(S)-1·HClO4] and (S)-2-(methyldiphenylsilyl)pyrrolidine [(S)-2·HClO4], the trifluoroacetate (S)-2·TFA, and the methanol-including hydrochloride (S)-1·HCl·MeOH were elucidated by X-ray crystallography and discussed in terms of hydrogen-bond interactions.en
dc.identifier.urihttp://hdl.handle.net/2003/38488
dc.identifier.urihttp://dx.doi.org/10.17877/DE290R-20407
dc.language.isoende
dc.relation.ispartofseriesInorganics;Jg.: 5, Heft: 4 | S. 88-1-88-8
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/
dc.subjectHydrogen bondsen
dc.subjectSiliconen
dc.subject2-silylpyrrolidinesen
dc.subjectStereochemistryen
dc.subjectX-ray crystallographyen
dc.subject.ddc540
dc.subject.rswkWasserstoffbrückenbindungde
dc.subject.rswkSiliciumde
dc.subject.rswkSilylverbindungende
dc.subject.rswkStereochemiede
dc.subject.rswkRöntgenkristallographiede
dc.titleMolecular structures of enantiomerically-pure (S)-2-(triphenylsilyl)- and (S)-2-(methyldiphenylsilyl)pyrrolidinium saltsen
dc.typeTextde
dc.type.publicationtypearticlede
dcterms.accessRightsopen access
eldorado.secondarypublicationtruede
eldorado.secondarypublication.primarycitationInorganics : Jg.: 5, 2017, Heft: 4 | S. 88-1-88-8de
eldorado.secondarypublication.primaryidentifierhttps://doi.org/10.3390/inorganics5040088de

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