Nonstatistical assembly of multicomponent [Pd2ABCD] cages

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dc.contributor.authorWu, Kai
dc.contributor.authorBenchimol, Elie
dc.contributor.authorBaksi, Ananya
dc.contributor.authorClever, Guido H.
dc.date.accessioned2024-08-15T13:23:57Z
dc.date.available2024-08-15T13:23:57Z
dc.date.issued2024-01-19
dc.description.abstractSelf-assembled hosts, inspired by biological receptors and catalysts, show potential for sustainable synthesis, energy conversion and medicine. Implementing multiple functionalities in the form of distinguishable building blocks, however, is difficult without risking narcissistic self-sorting or statistical mess. Here, we report a systematic series of integratively self-assembled heteroleptic cages in which two square-planar PdII cations are bridged by four different bis-pyridyl ligands A, B, C and D via synergistic effects to exclusively form a single isomer — the lantern-shaped cage [Pd2ABCD]. This self-sorting goal — forming just one out of 55 possible structures — is reached under full thermodynamic control and can be realized progressively (by combining progenitors such as [Pd2A2C2] with [Pd2B2D2]), directly from ligands and PdII cations, or by mixing all four corresponding homoleptic cages. The rational design of complex multicomponent assemblies that enables the incorporation of chemical moieties in a modular approach will advance their potential applications in functional nanosystems.en
dc.identifier.urihttp://hdl.handle.net/2003/42650
dc.identifier.urihttp://dx.doi.org/10.17877/DE290R-24487
dc.language.isoende
dc.subjectcoordination cagesen
dc.subjectsupramolecular chemistryen
dc.subjectself sortingen
dc.subject.ddc540
dc.titleNonstatistical assembly of multicomponent [Pd2ABCD] cagesen
dc.typeTextde
dc.type.publicationtypeResearchArticlede
dcterms.accessRightsopen access
eldorado.openaire.projectidentifierinfo:eu-repo/grantAgreement/EC/H2020/683083/EU/Reactivity and Assembly of Multifunctional, Stimuli-responsive Encapsulation Structures/RAMSESde
eldorado.secondarypublicationtruede
eldorado.secondarypublication.primarycitationWu, K., Benchimol, E., Baksi, A. Clever, G. H., Non-statistical assembly of multicomponent [Pd2ABCD] cages. Nat. Chem. 16, 584–591 (2024).de
eldorado.secondarypublication.primaryidentifierhttps://doi.org/10.1038/s41557-023-01415-7de

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