Multiple quantum NMR excitation with a one-quantum Hamiltonian
dc.contributor.author | Suter, Dieter | |
dc.contributor.author | Liu, S. B. | |
dc.contributor.author | Pines, A. | |
dc.date.accessioned | 2008-05-29T12:37:20Z | |
dc.date.available | 2008-05-29T12:37:20Z | |
dc.date.issued | 2001-11-16 | |
dc.description.abstract | Excitation of multiple quantum coherence in dipolar coupled spin systems is usually accomplished with a two-quantum multiple pulse sequence which can be time reversed by means of a 90° phase shift. The application of such an excitation scheme to a spin system in thermal equilibrium excites only even orders of multiple quantum coherence. We demonstrate here time reversible pulse sequences that excite all orders of coherence by creating a pure one-quantum average hamiltonian. We also describe pulse schemes which can be used to create pure one- or two-quantum average hamiltonians with variable scaling between +1 and −1. These excitation schemes are relevant to the study of spin clustering by multiple quantum NMR. | en |
dc.identifier.citation | Suter, D.; Liu, S. B.; Pines, A.: Multiple quantum NMR excitation with a one-quantum Hamiltonian. In: Chemical Physics Nr. 1, Jg. 114(1987, S. 103-109. | de |
dc.identifier.doi | 10.1016/0301-0104(87)80023-X | |
dc.identifier.uri | http://hdl.handle.net/2003/25321 | |
dc.identifier.uri | http://dx.doi.org/10.17877/DE290R-4001 | |
dc.language.iso | en | de |
dc.publisher | Elsevier | de |
dc.rights | Copyright © 1987 Published by Elsevier Science B.V. All rights reserved. | en |
dc.subject.ddc | 530 | |
dc.title | Multiple quantum NMR excitation with a one-quantum Hamiltonian | en |
dc.type | Text | de |
dc.type.publicationtype | article | de |
dcterms.accessRights | restricted | |
eldorado.identifier.url | http://e3.physik.tu-dortmund.de/~suter/eprints/SingleQuantumExcitation.pdf |
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