Implementation of coherent Raman detected electron paramagnetic resonance

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dc.contributor.advisorSuter, D.de
dc.contributor.authorGutschank, Jörgde
dc.contributor.refereeBöhmer, R.de
dc.date.accepted2005
dc.date.accessioned2005-01-31T08:06:23Z
dc.date.available2005-01-31T08:06:23Z
dc.date.created2005-01-14de
dc.date.issued2005-01-17de
dc.description.abstractThe technique of coherent Raman (optically) detected electron paramagnetic resonance (ODEPR), is a relatively new method for the investigation of electronic structure. In this thesis the technique is implemented with a microwave frequency of 35 GHz for the first time. Two continuous wave (cw) ODEPR spectrometers have been built (14 and 35 GHz). Pulsed microwave excitation is possible at 14 GHz. The application to ruby demonstrates the working of the technique and the equipment. When ODEPR is used to analyse metalloproteins, conventional methods like electron paramagnetic resonance (EPR) and magnetic circular dichroism (MCD) are additionally needed. These have also been implemented and they are demonstrated on myoglobin (Mb).en
dc.description.abstractThe technique of coherent Raman (optically) detected electron paramagnetic resonance (ODEPR), is a relatively new method for the investigation of electronic structure. In this thesis the technique is implemented with a microwave frequency of 35 GHz for the first time.Two continuous wave (cw) ODEPR spectrometers have been built (14 and 35 GHz). Pulsed microwave excitation is possible at 14 GHz.The application to ruby demonstrates the working of the technique and the equipment.When ODEPR is used to analyse metalloproteins, conventional methods like electron paramagnetic resonance (EPR) and magnetic circular dichroism (MCD) are additionally needed. These have also been implemented and they are demonstrated on myoglobin (Mb).en
dc.format.extent5224985 bytes
dc.format.mimetypeapplication/pdf
dc.identifier.urihttp://hdl.handle.net/2003/20034
dc.identifier.urihttp://dx.doi.org/10.17877/DE290R-14838
dc.language.isoende
dc.publisherUniversität Dortmundde
dc.subjectElektronenspinresonanzde
dc.subjectKohärente Raman-Streuungde
dc.subjectElectron spin resonanceen
dc.subjectESRen
dc.subjectCoherent Raman scatteringen
dc.subject.ddc530de
dc.titleImplementation of coherent Raman detected electron paramagnetic resonanceen
dc.typeTextde
dc.type.publicationtypedoctoralThesisde
dcterms.accessRightsopen access

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