Homogeneous catalysis at its edge: high-temperature Ru-catalysed amination of alcohols under continuous flow conditions

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dc.contributor.authorHeider, Christian
dc.contributor.authorWinter, Alina
dc.contributor.authorVoß, Viktoria
dc.contributor.authorVogt, Dieter
dc.contributor.authorSeidensticker, Thomas
dc.date.accessioned2025-03-18T14:55:44Z
dc.date.available2025-03-18T14:55:44Z
dc.date.issued2023-01-20
dc.description.abstractCombining a tubular flow reactor with a robust homogeneous catalyst enabled running the alcohol amination at unique conditions, i. e., very high temperatures at low residence times. Catalytic activities were thus increased to unprecedented values of >900 h−1 in the synthesis of tertiary dimethylalkylamines directly from alcohols with excellent selectivities exceeding 99 %. Furthermore, several alcohols could be converted to the desired tertiary amines.en
dc.identifier.urihttp://hdl.handle.net/2003/43552
dc.identifier.urihttp://dx.doi.org/10.17877/DE290R-25385
dc.language.isoen
dc.relation.ispartofseriesChemCatChem; 15(5)
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.subjectHomogeneous catalysisen
dc.subjectFlow chemistryen
dc.subjectAmine synthesisen
dc.subject.ddc660
dc.titleHomogeneous catalysis at its edge: high-temperature Ru-catalysed amination of alcohols under continuous flow conditionsen
dc.typeText
dc.type.publicationtypeResearchArticle
dcterms.accessRightsopen access
eldorado.secondarypublicationtrue
eldorado.secondarypublication.primarycitationC. Heider, A. Winter, V. Voß, D. Vogt, T. Seidensticker, ChemCatChem 2023, 15, e202201307.
eldorado.secondarypublication.primaryidentifierhttps://doi.org/10.1002/cctc.202201307

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