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DC Element | Wert | Sprache |
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dc.contributor.author | Bloch, Witold M. | - |
dc.contributor.author | Holstein, Julian J. | - |
dc.contributor.author | Dittrich, Birger | - |
dc.contributor.author | Hiller, Wolf | - |
dc.contributor.author | Clever, Guido H. | - |
dc.date.accessioned | 2018-04-12T10:54:49Z | - |
dc.date.available | 2018-04-12T10:54:49Z | - |
dc.date.issued | 2018-03-22 | - |
dc.identifier.uri | http://hdl.handle.net/2003/36832 | - |
dc.identifier.uri | http://dx.doi.org/10.17877/DE290R-18833 | - |
dc.description.abstract | The self‐assembly of eight PdII cations and sixteen phenanthrene‐derived bridging ligands with 60° bite angles yielded a novel M8L16 metallosupramolecular architecture composed of two interlocked D4h‐symmetric barrel‐shaped containers. Mass spectrometry, NMR spectroscopy, and X‐ray analysis revealed this self‐assembled structure to be a very large “Hopf link” catenane featuring channel‐like cavities, which are occupied by NO3− anions. The importance of the anions as catenation templates became imminent when we observed the nitrate‐triggered structural rearrangement of a mixture of M3L6 and M4L8 assemblies formed in the presence of BF4− anions into the same interlocked molecule. Furthermore, the densely packed structure of the M8L16 catenane was exploited in the preparation of a hexyloxy‐functionalized analogue, which further self‐assembled into vesicle‐like aggregates in a reversible manner. | en |
dc.language.iso | en | de |
dc.rights.uri | https://creativecommons.org/licenses/by-nc/4.0/ | - |
dc.subject | Catenanes | en |
dc.subject | Interlocked structures | en |
dc.subject | Self-assembly | en |
dc.subject | Structural transformations | en |
dc.subject | Supramolecular chemistry | en |
dc.subject.ddc | 540 | - |
dc.title | Hierarchical assembly of an interlocked M8L16 container | en |
dc.type | Text | de |
dc.type.publicationtype | article | de |
dcterms.accessRights | open access | - |
eldorado.openaire.projectidentifier | info:eu-repo/grantAgreement/EC/H2020/683083/EU/Reactivity and Assembly of Multifunctional, Stimuli-responsive Encapsulation Structures/RAMSES | de |
eldorado.secondarypublication | true | de |
eldorado.secondarypublication.primaryidentifier | DOI: 10.1002/anie.201800490 | de |
eldorado.secondarypublication.primarycitation | Bloch, W.M. et al, . Hierarchical Assembly of an Interlocked M8L16 Container. in: Angewandte Chemie, international Edition. 57. 2018, 10.1002/anie.201800490 | de |
Enthalten in den Sammlungen: | Lehrstühle für Anorganische Chemie |
Dateien zu dieser Ressource:
Datei | Beschreibung | Größe | Format | |
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Hierarchical Assembly of an Interlocked M8L16 Container_open_access.pdf | 2.29 MB | Adobe PDF | Öffnen/Anzeigen |
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