Authors: Li, Rujin
Title: Supramolecular coordination cages based on light-switchable diarylethene ligands
Language (ISO): en
Abstract: Supramolecular coordination cages, assembled from square-planer cations (PdII or PtII) and banana-shaped ligands, have been widely studied in the past decades. Interests in this field gradually shifted from structure to function. This thesis explores the self-assembly of light-switchable homo- and hetero-leptic cages formed by Diarylethene (DAE) ligands which enable a fast photo-responsive interconversion between a flexible open form and rigid closed form of the chromophore backbone. In addition, the host-guest chemistry, their application in photo-controlled chirality transfer and singlet oxygen generation are investigated.
Subject Headings: Coordination cage
Diarylethene
Light-switchable
Photochemistry
Subject Headings (RSWK): Koordinationschemie
Photochemie
URI: http://hdl.handle.net/2003/38130
http://dx.doi.org/10.17877/DE290R-20111
Issue Date: 2019
Appears in Collections:Lehrstühle für Anorganische Chemie

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