Full metadata record
DC FieldValueLanguage
dc.contributor.advisorClever, Guido-
dc.contributor.authorChen, Bin-
dc.date.accessioned2019-07-17T07:56:48Z-
dc.date.available2019-07-17T07:56:48Z-
dc.date.issued2019-
dc.identifier.urihttp://hdl.handle.net/2003/38145-
dc.identifier.urihttp://dx.doi.org/10.17877/DE290R-20124-
dc.description.abstractThis thesis showcases the donor-site engineering in PdII-mediated coordination complexes, yielding distinctive supramolecular architectures, including the molecular cage, bowl, ring and capsule focuses on the donor-site-controlled self-assembly of supramolecules as well as their distinct fullerene binding abilities. Afterwards, the assembled cage is able to selectively bind C60 from fullerene soot, and develops into a recyclable system of C60 purification controlled by solvent effects. The novel bowl structure is not only found to serve as a supramolecular protecting group, which allows selective mono-functionalization of its guest, but is also capable of being connected by a second ligand to hierarchically assemble into a molecular capsule which can accommodate two fullerene molecules within its inner cavity. In addition, a non-traditional nitrogen donor, namely naphthyridine, is shown to manifest a dislocated arrangement in the PdII coordination sphere owing to the repulsive effect between adjacent electron-pairs. A synergy between quinoline donors and naphthyridine donors as well as template effect of guests is further exploited to generate heteroleptic cages. At last, a newly designed fullerene-based ligand can assemble with PdII into a coordination cage bearing four fullerene molecules in the periphery. All compounds have been fully characterized by multiple analytic techniques, such as NMR spectroscopy, mass spectrometry and single crystal X-ray structural analysis.de
dc.language.isoende
dc.subjectSupramolecular chemistryde
dc.subjectSelf-assemblyde
dc.subjectCoordination cagede
dc.subjectFullerenede
dc.subjectFunctionalizationde
dc.subjectFullerene separationde
dc.subject.ddc540-
dc.titleControlled self‐assembly of cage‐like structures and their applications in fullerene chemistryde
dc.typeTextde
dc.contributor.refereeHenke, Sebastian-
dc.date.accepted2019-07-04-
dc.type.publicationtypedoctoralThesisde
dc.subject.rswkSupramolekulare Chemiede
dc.subject.rswkSelbstorganisationde
dc.subject.rswkKoordinationsverbindungende
dcterms.accessRightsopen access-
eldorado.secondarypublicationfalsede
Appears in Collections:Lehrstühle für Anorganische Chemie

Files in This Item:
File Description SizeFormat 
PhD thesis_Bin Chen.pdfDNB24.76 MBAdobe PDFView/Open


This item is protected by original copyright



Items in Eldorado are protected by copyright, with all rights reserved, unless otherwise indicated.