Authors: Bauer, Jonathan O.
Strohmann, Carsten
Title: Molecular structures of enantiomerically-pure (S)-2-(triphenylsilyl)- and (S)-2-(methyldiphenylsilyl)pyrrolidinium salts
Language (ISO): en
Abstract: Silyl-substituted pyrrolidines have gained increased interest for the design of new catalyst scaffolds. The molecular structures of four enantiomerically-pure 2-silylpyrrolidinium salts are reported. The perchlorate salts of (S)-2-(triphenylsilyl)pyrrolidine [(S)-1·HClO4] and (S)-2-(methyldiphenylsilyl)pyrrolidine [(S)-2·HClO4], the trifluoroacetate (S)-2·TFA, and the methanol-including hydrochloride (S)-1·HCl·MeOH were elucidated by X-ray crystallography and discussed in terms of hydrogen-bond interactions.
Subject Headings: Hydrogen bonds
Silicon
2-silylpyrrolidines
Stereochemistry
X-ray crystallography
Subject Headings (RSWK): Wasserstoffbrückenbindung
Silicium
Silylverbindungen
Stereochemie
Röntgenkristallographie
URI: http://hdl.handle.net/2003/38488
http://dx.doi.org/10.17877/DE290R-20407
Issue Date: 2017-12-06
Rights link: http://creativecommons.org/licenses/by/4.0/
Appears in Collections:Lehrstühle für Anorganische Chemie

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