Authors: | Bauer, Jonathan O. Strohmann, Carsten |
Title: | Molecular structures of enantiomerically-pure (S)-2-(triphenylsilyl)- and (S)-2-(methyldiphenylsilyl)pyrrolidinium salts |
Language (ISO): | en |
Abstract: | Silyl-substituted pyrrolidines have gained increased interest for the design of new catalyst scaffolds. The molecular structures of four enantiomerically-pure 2-silylpyrrolidinium salts are reported. The perchlorate salts of (S)-2-(triphenylsilyl)pyrrolidine [(S)-1·HClO4] and (S)-2-(methyldiphenylsilyl)pyrrolidine [(S)-2·HClO4], the trifluoroacetate (S)-2·TFA, and the methanol-including hydrochloride (S)-1·HCl·MeOH were elucidated by X-ray crystallography and discussed in terms of hydrogen-bond interactions. |
Subject Headings: | Hydrogen bonds Silicon 2-silylpyrrolidines Stereochemistry X-ray crystallography |
Subject Headings (RSWK): | Wasserstoffbrückenbindung Silicium Silylverbindungen Stereochemie Röntgenkristallographie |
URI: | http://hdl.handle.net/2003/38488 http://dx.doi.org/10.17877/DE290R-20407 |
Issue Date: | 2017-12-06 |
Rights link: | http://creativecommons.org/licenses/by/4.0/ |
Appears in Collections: | Lehrstühle für Anorganische Chemie |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
inorganics-05-00088.pdf | 2.15 MB | Adobe PDF | View/Open |
This item is protected by original copyright |
This item is licensed under a Creative Commons License