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dc.contributor.authorOtte, Felix-
dc.contributor.authorKoller, Stephan G.-
dc.contributor.authorGolz, Christopher-
dc.contributor.authorStrohmann, Carsten-
dc.date.accessioned2020-05-07T07:38:25Z-
dc.date.available2020-05-07T07:38:25Z-
dc.date.issued2016-09-30-
dc.identifier.urihttp://hdl.handle.net/2003/39101-
dc.identifier.urihttp://dx.doi.org/10.17877/DE290R-21019-
dc.description.abstractThe title compounds, [Sn3(CH3)9(OH)2(H2O)2][Sn(CH3)3(CHO2)2] (1) and [Sn3(CH3)9(OH)2]Cl·H2O (2), are partially condensed products of hydrolysed tri­methyl­tin chloride. In the structures of 1 and 2, short cationic tris­tannatoxanes (C9H29O2Sn3) are bridged by a diformatotri­methyl­tin anion or a chloride anion, respectively. Hydrogen bridges are present and supposedly stabilize these structures against further polymerization to the known polymeric tri­methyl­tin hydroxide. Especially noteworthy is that the formate present in this structure was formed from atmospheric CO2.en
dc.language.isoende
dc.relation.ispartofseriesActa Cryst. E;72(10)-
dc.rights.urihttps://creativecommons.org/licenses/by/2.0/uk/legalcode-
dc.subjectCrystal structureen
dc.subjectTinen
dc.subjectTrimethyltin hydroxideen
dc.subjectFormateen
dc.subjectChlorideen
dc.subjectHydrolysisen
dc.subjectHydrogen bondingen
dc.subject.ddc540-
dc.titleCrystal structures of di­aquadi-μ-hydroxido-tris­­[tri­methyl­tin(IV)] diformatotri­methyl­stannate(IV) and di-μ-hydroxido-tris­­[tri­methyl­tin(IV)] chloride monohydrateen
dc.typeTextde
dc.type.publicationtypearticlede
dcterms.accessRightsopen access-
eldorado.secondarypublicationtruede
eldorado.secondarypublication.primaryidentifierhttps://doi.org/10.1107/S2056989016014912de
eldorado.secondarypublication.primarycitationOtte, F; Koller, SG; Golz, C; Strohmann, C (2016): Crystal structures of di­aquadi-μ-hydroxido-tris­­[tri­methyl­tin(IV)] diformatotri­methyl­stannate(IV) and di-μ-hydroxido-tris­­[tri­methyl­tin(IV)] chloride monohydrate. Acta Cryst. E 72(10), 1499-1502de
Appears in Collections:Lehrstühle für Anorganische Chemie

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