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dc.contributor.authorBrieger, Lukas-
dc.contributor.authorJourdain, Isabelle-
dc.contributor.authorKnorr, Michael-
dc.contributor.authorStrohmann, Carsten-
dc.date.accessioned2020-05-07T07:59:34Z-
dc.date.available2020-05-07T07:59:34Z-
dc.date.issued2019-11-22-
dc.identifier.urihttp://hdl.handle.net/2003/39103-
dc.identifier.urihttp://dx.doi.org/10.17877/DE290R-21021-
dc.description.abstractThe title compound, [FePt(C12H12O)(C18H15P)(C25H22P2)(CO)2]·2C7H8·CH2Cl2 or [(OC)2Fe(μ-dppm)(μ-C(=O)C(2,4,5-C6H2Me3)=CH)Pt(PPh3)], represents an example of a diphosphane-bridged heterobimetallic dimetalla­cyclo­pentenone complex resulting from a bimetallic activation of 1-ethynyl-2,4,5-tri­methyl­benzene and a metal-coordinated carbonyl ligand. The bridging μ2-C(=O)C(2,4,5-C6H2Me3)=CH unit (stemming from a carbon–carbon coupling reaction between CO and the terminal alkyne) forms a five-membered dimetalla­cyclo­pentenone ring, in which the C=C bond is π-coordinated to the Fe centre. The latter is connected to the Pt centre through a short metal–metal bond of 2.5770 (5) Å. In the crystal, the complex is solvated by one di­chloro­methane and two toluene mol­ecules.en
dc.language.isoende
dc.relation.ispartofseriesActa Cryst. E;75(12)-
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/legalcode-
dc.subjectCrystal structureen
dc.subjectTerminal alkyneen
dc.subjectIronen
dc.subjectPlatinumen
dc.subjectHeterobimetallicen
dc.subjectMetal-metal bond dimetallacyclopentenoneen
dc.subjectBis(diphenylphosphino)methaneen
dc.subjectHydrogen bondingen
dc.subjectC—H⋯π inter­actionsen
dc.subject.ddc540-
dc.titleCrystal structure of dicarbonyl[μ2-methylenebis(diphenylphosphane)-κ2 P:P′][μ2-2-(2,4,5-trimethylphenyl)-3-oxoprop-1-ene-1,3-diyl](triphenylphosphane-κP)ironplatinum(Fe—Pt)–dichloromethane–toluene (1/1/2), [(OC)2Fe(μ-dppm)(μ-C(=O)C(2,4,5-C6H2Me3)=CH)Pt(PPh3)]en
dc.typeTextde
dc.type.publicationtypearticlede
dcterms.accessRightsopen access-
eldorado.secondarypublicationtruede
eldorado.secondarypublication.primaryidentifierhttps://doi.org/10.1107/S2056989019015573de
eldorado.secondarypublication.primarycitationBrieger, Lukas, Isabelle Jourdain, Michael Knorr, und Carsten Strohmann. "Crystal structure of dicarbonyl[μ2-methylenebis(diphenylphosphane)-κ2 P:P′][μ2-2-(2,4,5-trimethylphenyl)-3-oxoprop-1-ene-1,3-diyl](triphenylphosphane-κP)ironplatinum(Fe—Pt)–dichloromethane–toluene (1/1/2), [(OC)2Fe(μ-dppm)(μ-C(=O)C(2,4,5-C6H2Me3)=CH)Pt(PPh3)]." Acta Cryst. E 75, no. 12 (Dezember 2019): 1902-6.de
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