Authors: | Knauer, Lena Knorr, Michael Viau, Lydie Strohmann, Carsten |
Title: | Crystal structure of the coordination polymer catena-poly[[[(acetonitrile-κN)copper(I)]-μ3-1,3-dithiolane-κ3S:S:S′] hexafluoridophosphate] |
Language (ISO): | en |
Abstract: | The polymeric title compound, [Cu2(C2H3N)2(C3H6S2)2](PF6)2, represents an example of a one-dimensional coordination polymer resulting from the reaction of [Cu(MeCN)4][PF6] with 1,3-dithiolane. The cationic one-dimensional ribbon consists of two copper(I) centers each ligated by one acetonitrile molecule and interconnected through two bridging 1,3-dithiolane ligands. One S-donor site of each ligand is κ1-bound to Cu, whereas the second S atom acts as a four-electron donor, bridging two Cu atoms in a κ4-bonding mode. The positive charge of each copper cation is compensated for by a hexafluoridophosphate counter-ion. In the crystal, the polymer chains are linked by a series of C—H...F hydrogen bonds, forming a supramolecular framework |
Subject Headings: | Crystal structure Copper complex Coordination polymer Thioether C—H...F hydrogen bonding |
URI: | http://hdl.handle.net/2003/39127 http://dx.doi.org/10.17877/DE290R-21045 |
Issue Date: | 2019-12-19 |
Rights link: | http://creativecommons.org/licenses/by/4.0/ |
Appears in Collections: | Lehrstühle für Anorganische Chemie |
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su5530.pdf | 660.5 kB | Adobe PDF | View/Open |
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