Authors: Basu Baul, Tushar S.
Chaurasiya, Anurag
Rabha, Monosh
Khatua, Snehadrinarayan
Lyčka, Antonin
Schollmeyer, Dieter
Jurkschat, Klaus
Title: Diorganotin compounds containing α-aminoacidato schiff base ligands derived from functionalized 2-Hydroxy-5-(aryldiazenyl)benzaldehyde
Other Titles: syntheses, structures and sensing of hydrogen sulfide
Language (ISO): en
Abstract: Three novel bicycloazastannoxides, namely, [nBu2Sn(L1)] (1), [nBu2Sn(L2)] (2) and [Bz2Sn(L3)] (3) were synthesized in one pot procedures by reacting diorganotin(IV) precursors with a mixture composed of an α-amino acid with either (E)-2-hydroxy-5-((4-nitrophenyl)diazenyl)benzaldehyde or (E)-2-hydroxy-5-(phenyldiazenyl)benzaldehyde. Single-crystal X-ray diffraction analysis reveal that compound 1 is monomeric, compound 2 consists of both a monomer and a dimer, while compound 3 is a coordination polymer for which two modifications 3A and 3B were identified. The 119Sn NMR chemical shifts measured in CDCl3 solutions indicate five-coordinate tin atoms for 1–3. Further, compounds 1 and 2 were found to be highly selective for sensing hydrogen sulfide in UV/Vis channel in CH3CN/H2O (9:1) media. The development of orange red color is likely the results of a Brønsted-type acid-base reaction of H2S with compounds 1 and 2, respectively, giving di-n-butyltin sulfide and the corresponding pro-ligands H2L1 and H2L2, respectively. Theoretical calculations accompany the experimental work.
Subject Headings: Tin
Ligands with azo-imino groups
Structure elucidation
Sensing studies
Issue Date: 2020-04-03
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Appears in Collections:Lehrstühle für Anorganische Chemie

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