Authors: Alashkar, Nour
Arca, Massimiliano
Alnasr, Hazem
Lutter, Michael
Lippolis, Vito
Title: Water-soluble organotin compounds
Other Titles: syntheses, structures and reactivity towards fluoride anion in water
Language (ISO): en
Abstract: Herein, we report the syntheses of the water-soluble organotin compounds [{Me2(H)N(CH2)3}2SnX2]Y2 (1, X = Cl, Y = ClO4; 2, X = F, Y = ClO4) and {Me2(H)N(CH2)3}2SnX4 (3, X = Cl; 4, X = F). The compounds were characterized by elemental analysis, electrospray mass spectrometry, 1H, 13C, 19F, and 119Sn NMR spectroscopy, and in the case of compounds 1, 3 and 4, by single-crystal X-ray diffraction analysis. The reaction of compound 2 with fluoride anions in water was investigated by NMR spectroscopy. DFT calculations accompany the experimental work.
Subject Headings: Tin
Lewis acids
Structure elucidation
Density functional calculations
Issue Date: 2020-08-21
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Appears in Collections:Lehrstühle für Anorganische Chemie

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