Authors: | Achternbosch, Moritz Brieger, Lukas Strohmann, Carsten |
Title: | Influence of lithium coordinating additives on the structure of phenyldimethylsilyllithium |
Language (ISO): | en |
Abstract: | The synthesis and structural investigation of two dimethylphenylsilyllithium adducts with coordinating nitrogen donors quinuclidine and 1,3,5-tri-tert-butylhexahydro-1,3,5-triazine (tbtac) are presented. The structures show a comparatively long Si−Li distance and one amongst the shortest in monomeric silyllithiums reported so far, respectively. The structural investigations shed light on the influence of the donating additive for the lithium center on the structure of silyllithium compounds. |
Subject Headings: | Lithiosilane Silanides Lithium Silicon Reductions |
URI: | http://hdl.handle.net/2003/40848 http://dx.doi.org/10.17877/DE290R-22705 |
Issue Date: | 2021-03-22 |
Rights link: | https://creativecommons.org/licenses/by-nc-nd/4.0/ |
Appears in Collections: | Lehrstühle für Anorganische Chemie |
Files in This Item:
File | Description | Size | Format | |
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Zeitschrift anorg allge chemie - 2021 - Achternbosch - Influence Of Lithium Coordinating Additives On The Structure Of.pdf | DNB | 1.86 MB | Adobe PDF | View/Open |
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