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dc.contributor.authorHares, Kevin-
dc.contributor.authorVogelsang, Dennis-
dc.contributor.authorWernsdörfer, Charlotte S.-
dc.contributor.authorPanke, Dennis-
dc.contributor.authorVogt, Dieter-
dc.contributor.authorSeidensticker, Thomas-
dc.date.accessioned2023-03-17T08:25:10Z-
dc.date.available2023-03-17T08:25:10Z-
dc.date.issued2022-05-02-
dc.identifier.urihttp://hdl.handle.net/2003/41295-
dc.identifier.urihttp://dx.doi.org/10.17877/DE290R-23138-
dc.description.abstractFor the first time, mixed carboxylic anhydrides were accessed directly via homogeneous palladium catalysis from 1,3-butadiene and carboxylic acids. Under carbonylative telomerization conditions, the respective mixed 3,8-nonadienoic anhydrides are formed in a single reaction step with yields of up to 82%. These very reactive mixed anhydrides can then be used for consecutive reactions in a one-pot manner and selectively transfer the newly formed unsaturated C9 unit. Possible changes in the proposed mechanism were discussed and in a first example, the mixed anhydrides were utilized to form amides.en
dc.language.isoende
dc.relation.ispartofseriesCatalysis science & technology;12(12)-
dc.rights.urihttps://creativecommons.org/licenses/by/3.0/-
dc.subject.ddc660-
dc.titlePalladium-catalyzed synthesis of mixed anhydrides via carbonylative telomerizationen
dc.typeTextde
dc.type.publicationtypearticlede
dcterms.accessRightsopen access-
eldorado.secondarypublicationtruede
eldorado.secondarypublication.primaryidentifierhttps://doi.org/10.1039/D2CY00486Kde
eldorado.secondarypublication.primarycitationCatal. Sci. Technol., 2022,12, 3992-4000de
Appears in Collections:Lehrstuhl Technische Chemie

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