Full metadata record
DC FieldValueLanguage
dc.contributor.authorXue, Wen-Long-
dc.contributor.authorKolodzeiski, Pascal-
dc.contributor.authorAucharova, Hanna-
dc.contributor.authorVasa, Suresh-
dc.contributor.authorKoutsianos, Athanasios-
dc.contributor.authorPallach, Roman-
dc.contributor.authorSong, Jianbo-
dc.contributor.authorFrentzel-Beyme, Louis-
dc.contributor.authorLinser, Rasmus-
dc.contributor.authorHenke, Sebastian-
dc.date.accessioned2024-09-04T12:18:23Z-
dc.date.available2024-09-04T12:18:23Z-
dc.date.issued2024-05-24-
dc.identifier.urihttp://hdl.handle.net/2003/42668-
dc.identifier.urihttp://dx.doi.org/10.17877/DE290R-24504-
dc.description.abstractBy combining the porosity of crystalline metal-organic frameworks (MOFs) with the unique processability of the liquid state, melt-quenched MOF glasses offer exciting opportunities for molecular separation. However, progress in this field is limited by two factors. Firstly, only very few MOFsmelt at elevated temperatures and transform into stable glasses upon cooling the correspondingMOF liquid. Secondly, theMOF glasses obtained thus far feature only very small porosities and very small pore sizes. Here, we demonstrate solventassisted linker exchange (SALE) as a versatile method to prepare highly porous melt-quenched MOF glasses from the canonical ZIF-8. Two additional organic linkers are incorporated into the non-meltable ZIF-8, yielding high-entropy, linker-exchanged ZIF-8 derivatives undergoing crystal-to-liquid-to-glass phase transitions by thermal treatment. The ZIF-8 glasses demonstrate specific pore volumes of about 0.2 cm3g–1, adsorb large amounts of technologically relevant C3 and C4 hydrocarbons, and feature high kinetic sorption selectivities for the separation of propylene from propane.en
dc.language.isoenen
dc.relation.ispartofseriesNature communications;15-
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/-
dc.subject.ddc540-
dc.titleHighly porous metal-organic framework liquids and glasses via a solvent-assisted linker exchange strategy of ZIF-8en
dc.typeTexten
dc.type.publicationtypeArticleen
dcterms.accessRightsopen access-
eldorado.secondarypublicationtruede
eldorado.secondarypublication.primaryidentifierhttps://doi.org/10.1038/s41467-024-48703-5de
eldorado.secondarypublication.primarycitationXue, W.-L. et al. (2024) ‘Highly porous metal-organic framework liquids and glasses via a solvent-assisted linker exchange strategy of ZIF-8’, Nature communications, 15. Available at: https://doi.org/10.1038/s41467-024-48703-5en
Appears in Collections:Lehrstühle für Anorganische Chemie

Files in This Item:
File Description SizeFormat 
s41467-024-48703-5(1).pdfDNB2.77 MBAdobe PDFView/Open


This item is protected by original copyright



This item is licensed under a Creative Commons License Creative Commons