A nuclear magnetic resonance study of higher-order correlation functions in supercooled ortho-terphenyl

dc.contributor.authorBöhmer, Roland
dc.contributor.authorDiezemann, G.
dc.contributor.authorSillescu, H.
dc.contributor.authorHinze, G.
dc.date.accessioned2008-06-12T11:11:35Z
dc.date.available2008-06-12T11:11:35Z
dc.date.issued1998-01-15
dc.description.abstractUsing deuteron NMR techniques two-, effective three-, and various four-time correlation functions were recorded for supercooled ortho-terphenyl at 10–15 K above the calorimetric glass transition in order to characterize the heterogeneous nature of its primary response. The experimental results could successfully be described within various energy landscape models as well as via continuous time random walk simulations. These theoretical considerations provide a suitable basis for a definition of the term dynamic heterogeneity. We discuss the power but also some limitations of the present multidimensional NMR techniques when applied to amorphous materialsen
dc.identifier.citationBöhmer, R.; Diezemann, G.; Hinze, G.; Sillescu, H.: A nuclear magnetic resonance study of higher-order correlation functions in supercooled ortho-terphenyl. In: Journal of Chemical Physics Nr. 3, Jg. 108(1998), S. 890-899, doi: 10.1063/1.475452.de
dc.identifier.doi10.1063/1.475452
dc.identifier.urihttp://hdl.handle.net/2003/25527
dc.identifier.urihttp://dx.doi.org/10.17877/DE290R-3312
dc.identifier.urlhttp://dx.doi.org/ 10.1063/1.475452
dc.language.isoende
dc.publisherAmerican Institute of Physicsen
dc.rights©1998 American Institute of Physicsen
dc.subject.ddc530
dc.titleA nuclear magnetic resonance study of higher-order correlation functions in supercooled ortho-terphenylen
dc.typeTextde
dc.type.publicationtypearticlede
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