Stimulated 7^Li echo NMR spectroscopy of slow ionic motions in a solid electrolyte

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dc.contributor.authorBöhmer, Roland
dc.contributor.authorJörg, T.
dc.contributor.authorQi, F.
dc.contributor.authorTitze, A.
dc.date.accessioned2008-06-10T14:43:01Z
dc.date.available2008-06-10T14:43:01Z
dc.date.issued2000-01-24
dc.description.abstractLithium spin-alignment spectroscopy is presented as an NMR technique for studying slow translational motions in solid and solid-like ionic conductors. We employ phase cycling that allows to measure two-time translational correlation functions via the generation of a pure quadrupolar ordered state. Correlation functions of the crystalline electrolyte Li3Sc2(PO4)3 were recorded for times ranging from about 0.1 ms to more than 10 s, implying that translational diffusion coefficients smaller than 10^−20 m^2/s become accessible.en
dc.identifier.citationLithium spin-alignment spectroscopy is presented as an NMR technique for studying slow translational motions in solid and solid-like ionic conductors. We employ phase cycling that allows to measure two-time translational correlation functions via the generation of a pure quadrupolar ordered state. Correlation functions of the crystalline electrolyte Li3Sc2(PO4)3 were recorded for times ranging from about 0.1 ms to more than 10 s, implying that translational diffusion coefficients smaller than 10-20 m2/s become accessible.de
dc.identifier.doi10.1016/S0009-2614(99)01297-X
dc.identifier.urihttp://hdl.handle.net/2003/25491
dc.identifier.urihttp://dx.doi.org/10.17877/DE290R-3491
dc.identifier.urlhttp://dx.doi.org/10.1016/S0009-2614(99)01297-X
dc.language.isoende
dc.publisherElsevierde
dc.rightsCopyright © 2000 Elsevier Science B.V. All rights reservedde
dc.subject.ddc530
dc.titleStimulated 7^Li echo NMR spectroscopy of slow ionic motions in a solid electrolyteen
dc.typeTextde
dc.type.publicationtypearticlede
dcterms.accessRightsrestricted

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