Implementation of coherent Raman detected electron paramagnetic resonance

Gutschank, Jörg

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DC Element	Wert	Sprache
dc.contributor.advisor	Suter, D.	de
dc.contributor.author	Gutschank, Jörg	de
dc.date.accessioned	2005-01-31T08:06:23Z	-
dc.date.available	2005-01-31T08:06:23Z	-
dc.date.created	2005-01-14	de
dc.date.issued	2005-01-17	de
dc.identifier.uri	http://hdl.handle.net/2003/20034	-
dc.identifier.uri	http://dx.doi.org/10.17877/DE290R-14838	-
dc.description.abstract	The technique of coherent Raman (optically) detected electron paramagnetic resonance (ODEPR), is a relatively new method for the investigation of electronic structure. In this thesis the technique is implemented with a microwave frequency of 35 GHz for the first time. Two continuous wave (cw) ODEPR spectrometers have been built (14 and 35 GHz). Pulsed microwave excitation is possible at 14 GHz. The application to ruby demonstrates the working of the technique and the equipment. When ODEPR is used to analyse metalloproteins, conventional methods like electron paramagnetic resonance (EPR) and magnetic circular dichroism (MCD) are additionally needed. These have also been implemented and they are demonstrated on myoglobin (Mb).	en
dc.description.abstract	The technique of coherent Raman (optically) detected electron paramagnetic resonance (ODEPR), is a relatively new method for the investigation of electronic structure. In this thesis the technique is implemented with a microwave frequency of 35 GHz for the first time.Two continuous wave (cw) ODEPR spectrometers have been built (14 and 35 GHz). Pulsed microwave excitation is possible at 14 GHz.The application to ruby demonstrates the working of the technique and the equipment.When ODEPR is used to analyse metalloproteins, conventional methods like electron paramagnetic resonance (EPR) and magnetic circular dichroism (MCD) are additionally needed. These have also been implemented and they are demonstrated on myoglobin (Mb).	en
dc.format.extent	5224985 bytes	-
dc.format.mimetype	application/pdf	-
dc.language.iso	en	de
dc.publisher	Universität Dortmund	de
dc.subject	Elektronenspinresonanz	de
dc.subject	Kohärente Raman-Streuung	de
dc.subject	Electron spin resonance	en
dc.subject	ESR	en
dc.subject	Coherent Raman scattering	en
dc.subject.ddc	530	de
dc.title	Implementation of coherent Raman detected electron paramagnetic resonance	en
dc.type	Text	de
dc.contributor.referee	Böhmer, R.	de
dc.date.accepted	2005	-
dc.type.publicationtype	doctoralThesis	de
dcterms.accessRights	open access	-
Enthalten in den Sammlungen:	Experimentelle Physik III

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