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dc.contributor.advisorSuter, Dieterde
dc.contributor.authorBörger-Enkisch, Birgitde
dc.date.accessioned2004-12-06T11:26:27Z-
dc.date.available2004-12-06T11:26:27Z-
dc.date.created2001-06-29de
dc.date.issued2001-08-13de
dc.identifier.urihttp://hdl.handle.net/2003/2340-
dc.identifier.urihttp://dx.doi.org/10.17877/DE290R-14805-
dc.description.abstractMetalloproteins, that is proteins containing metal ions, play a key role in biochemical processess. This thesis presents a novel spectroscopic technique, optically detected electron paramagnetic resonance (ODEPR) spectroscopy, which can be applied to the study of metalloproteins. In this work experimental results from different biological samples are presented, where we focus on the copper protein azurin and the iron-sulfurprotein rubredoxin. In addition, the ODEPR spectra are interpreted by means of a theoretical model, which leads to the determination of key parameters such as the optical polarisation of the involved transitions. This thesis demonstrates that ODEPR spectroscopy can serve to improve our understanding of the electronic structure of metalloproteins, and to complement standard spectroscopy methods.en
dc.format.extent5713268 bytes-
dc.format.extent2548069 bytes-
dc.format.mimetypeapplication/postscript-
dc.format.mimetypeapplication/pdf-
dc.language.isoende
dc.publisherUniversität Dortmundde
dc.subjectElektronenspinresonanzde
dc.subjectKohärente Ramanstreuungde
dc.subjectAzurinde
dc.subjectRubredoxinde
dc.subjectmagnetischer Zirkulardichroismusde
dc.subjectelectron paramagnetc resonanceen
dc.subjectAzurin, Rubredoxinde
dc.subjectmagnetic circular dichroismen
dc.subjectcoherent Raman scatteringen
dc.subjectmetalloproteinsen
dc.subjectEPRde
dc.subject.ddc530de
dc.titleOptically detected Electron Paramagnetic Resonance of Metalloproteinsen
dc.typeTextde
dc.contributor.refereeThomson, A. J.de
dc.date.accepted2001-
dc.type.publicationtypedoctoralThesisde
dcterms.accessRightsopen access-
Appears in Collections:Experimentelle Physik III

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