Authors: Suter, Dieter
Schenker, K. V.
Pines, A.
Title: Theory of broadband heteronuclear decoupling in multispin systems
Language (ISO): en
Abstract: The Waugh theory of broadband decoupling in NMR for I-S Spin 1/2 pairs is extended to arbitrary spin systems. It is shown that complete decoupling is achieved over a certain bandwidth if the irradiation scheme generates an average Hamiltonian for the I spins whose eigenvectors and eigenvalues are independent of resonance offset. If the observed S spins are only weakly coupled, it is possible to calculate the resulting spectrum directly from the offset dependence of the average Hamiltonian of the isolated I-spin system under the influence of the periodic decoupling sequence. The treatment applies to indirectly observed multiple-quantum transitions as well as to directly observable single-quantum resonance lines.
URI: http://hdl.handle.net/2003/25322
http://dx.doi.org/10.17877/DE290R-3486
Publishers Link: http://e3.physik.tu-dortmund.de/~suter/eprints/BBdecoupling_Theory.pdf
Issue Date: 2004-07-13
Rights: Copyright © 1987 Published by Elsevier Inc.
Publisher: Elsevier
Citation: Suter, D.; Schenker, K. V.; Pines, A.: Theory of broadband heteronuclear decoupling in multispin systems. In: Journal of Magnetic Resonance Nr. 1, Jg. 73(1987), S. 90-98.
Appears in Collections:Suter, Dieter Prof. Dr.

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