|Title:||Phase transition kinetics and reorientational dynamics of the plastic crystal meta-carborane studied by deuteron NMR|
|Abstract:||Meta-carborane shows an orientationally disordered, orthorhombic phase which transforms into an ordered monoclinic phase near 170 K and into a quasi-isotropic cubic phase near 280 K. From deuteron magnetization measurements both transitions are found to exhibit a thermal hysteresis and slow transformation kinetics. Furthermore, solid-echo NMR spectra and spin-lattice relaxation times are reported. These results indicate that in the orthorhombic phase the meta-carborane molecules perform a strongly anisotropic motion which is characterized by a temperature dependent amplitude.|
|Rights:||Copyright © 2002 Elsevier Science B.V. All rights reserved.|
|Citation:||Winterlich, M.; Böhmer, R.; Zimmermann, H.. Phase transition kinetics and reorientational dynamics of the plastic crystal meta-carborane studied by deuteron NMR. In: Journal of Non-Crystalline Solids Jg. 307-310(2002), S. 442-448, doi: 10.1016/S0022-3093(02)01506-5.|
|Appears in Collections:||Böhmer, Roland Prof. Dr.|
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