Authors: Brieger, Lukas
Hermann, Andreas
Unkelbach, Christian
Strohmann, Carsten
Title: Crystal structure and quantum-chemical calculations of a tri­methyl­aluminium–THF adduct
Language (ISO): en
Abstract: The title compound, trimeth­yl(tetra­hydro­furan-κO)aluminium(III), [Al(CH3)3(C4H8O)], is an addition product of tri­methyl­aluminium and tetra­hydro­furan (THF). Instead of a dimeric structure, which is very common for these types of compounds, a monomeric mol­ecular structure is observed. The C—Al—C angles in the mol­ecule are very different from the C—Al—C angles found in dimeric mol­ecular structures, leading to a different symmetry around the AlIII atom. The reasons for these differences are discussed.
Subject Headings: Crystal structure
Aluminium
Trimethylaluminium
THF
Adduct
Monomer
Angle
URI: http://hdl.handle.net/2003/39102
http://dx.doi.org/10.17877/DE290R-21020
Issue Date: 2018-01-31
Rights link: https://creativecommons.org/licenses/by/2.0/uk/legalcode
Appears in Collections:Lehrstühle für Anorganische Chemie

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